One method of creating a brass coating is through electrodeposition, which most often completed in cyanide galvanic baths. Due to their toxicity, many investigations focused on the development more environmentally friendly alternatives. The purpose study was explore new generation non-aqueous cyanide-free baths based 1-ethyl-3-methylimidazolium acetate ionic liquids. involved formation copper, ...

In this paper, Fe3O4-chitosan nanoparticles were prepared by the immobilization of chitosan on the surface of Fe3O4 nanoparticles. Then, the 5-substituted hydantoins were synthesized from the condensation of aldehyde derivatives, ammonium carbonate and zinc cyanide as a well-known cyanating agent by the magnetic Fe3O4-chitosan nanoparticles under neat conditions. Fe3O4-Chitosan nanocatalyst as ...

Capillary zone electrophoresis with on-column UV detection at 214 nm was used to detect and determine iron cyanide complexes in liquid samples from zinc electroplating processes. Using a cathodic injection and anodic detection scheme, hexacyanoferrate(T1) and -(III) ions were separated with baseline resolution in under 5 min. A linear relationship between peak area and concentration was obtaine...

The first section of this chapter describes general pollution prevention techniques for plating solutions and covers housekeeping, monitoring, additives, equipment modification, and on-site recycling and recovery. The next section covers general issues in pollution prevention for cyanide-based plating. The next seven sections cover pollution prevention options for plating specific metals such a...

In this paper, Fe3O4-chitosan nanoparticles were prepared by the immobilization of chitosan on the surface of Fe3O4 nanoparticles. Then, the 5-substituted hydantoins were synthesized from the condensation of aldehyde derivatives, ammonium carbonate and zinc cyanide as a well-known cyanating agent by the magnetic Fe3O4-chitosan nanoparticles under neat conditions. Fe3O4-Chitosan nanocatalyst as ...

In this study, the designed dual stage membrane bioreactor (MBR) system was conceptualized for the treatment of cyanide and heavy metals in electroplating wastewater. The design consisted of a primary treatment stage to reduce the impact of fluctuations and the secondary treatment stage to remove the residual cyanide and heavy metal contaminants in the wastewater under alkaline pH conditions. T...

We describe in this study the asymmetric synthesis of radioisotope (RI)-labeled selective glucocorticoid receptor modulator. This synthesis is based on optimization of the cinchona alkaloid catalyzed addition of 6-bromoindole to ethyl trifluoropyruvate and Negishi coupling of zinc cyanide to the 6-bromoindole moiety. [¹⁴C] Labeled (-)-{4-[(1-{2-[6-cyano-1-(cyclohexylmethyl)-1H-indol-3-yl]-3,3,3...

Present article is devoted to study of electrolytic zinc powders usage features in gold mining industry. Electrolytic characterized by dendritic shape and a high specific surface area. These provide number advantages for cementation from alkaline cyanide solutions. Dendritic form powder makes it possible reduce layer hydraulic resistance on filtering surface, which important when using technolo...