iron (in zero-valent and oxide forms) is used to remove numerous organic and inorganic contaminants in environment. however, there are few reports, especially in nano scale, on the remediation of heavy metals contaminated soils using zero-valent iron in the literature. in this study, the effect of iron on the availability of heavy metals was evaluated in a calcareous soil spiked with cadmium, z...

Flow-through columns packed with "aged" zero-valent iron (ZVI) between layers of soil and sand were constructed to mimic a one-dimensional permeable reactive iron barrier (PRB). The columns were continuously fed RDX (hexahydro-1,3,5-trinitro-1,3,5-triazine, ca. 18 mg l(-1)) for over one year. Two columns were bioaugmented with dissimilatory iron reducing bacteria (DIRB) Shewanella algae BrY or ...

---------------------------------------------------------------------***--------------------------------------------------------------------Abstract The objective of this work is to study reduction of nitrate concentration using zero-valent iron (ZVI) which has its application in permeable reactive barriers (PRBs). Also, to find out effect of concrete penetrating corrosion inhibiting admixture ...

Permeable reactive barriers containing zerovalent iron are being increasingly employed for in situ remediation of groundwater contaminated with redox active metals and chlorinated organic compounds. This research investigated the effect of chromate concentration on its removal from solution by zerovalent iron. Removal rates of aqueous Cr(VI) by iron wires were measured in batch experiments for ...

Dechlorination reactions at sp(2) C-Cl bonds by a pentaphosphino zero-valent iron (ZVI) complex are proposed to follow an oxidative addition, β-Cl-elimination pathway en route to iron-chloride, iron-hydride and iron-acetylide products, the distribution being dependent on the nature of alkyne produced.

Anaerobic digestion has been widely applied for waste activated sludge (WAS) treatment. However, methane production from anaerobic digestion of WAS is usually limited by the slow hydrolysis rate and/or poor biochemical methane potential of WAS. This work systematically studied the effects of three different types of zero valent iron (i.e., iron powder, clean scrap and rusty scrap) on methane pr...

Granular zero-valent iron (ZVI) has been widely used to construct permeable reactive barriers (PRB) for the in situ remediation of groundwater contaminated with halogenated hydrocarbons. In the anaerobic condition of most groundwater flow systems, iron undergoes corrosion by water and results in hydrogen gas generation. Several studies have shown that some of the hydrogen gas generated at the i...

• ZVI-Cu/C composites were prepared from spent LIB anode and mill scale. High dispersed ZVI-Cu particles on graphite obtained after carbothermic reaction. Removal of 4-CP by reduction oxidation reactions. Hydroquinone 4-chlorocatechol identified as intermediate products degradation. has lower cost comparable performance with other catalysts for removal. Graphite supported zero-valent iron-coppe...

John T. Wilson While biologically mediated reductive dechlorination continues to be a significant focus of chlorinated solvent remediation, there has been an increased interest in abiotic reductive processes for the remediation of chlorinated solvents. In situ chemical reduction (ISCR) uses zero-valent iron (ZVI)–based technologies, such as nanoscale iron and bimetallic ZVI, as well as naturall...