To determine the relative importance of the confining geometry and nanoscopic length scale versus water/interface interactions, the dynamic interactions between water and interfaces are studied with ultrafast infrared spectroscopy. Aerosol OT (AOT) is a surfactant that can form two-dimensional lamellar structures with known water layer thickness as well as well-defined monodispersed spherical r...

We developed and tested a theoretical model for the attachment of fluid-infused porous supra-particles to a fluid-liquid interface. We considered the wetting behaviour of agglomerated clusters of particles, typical of powdered materials dispersed in a liquid, as well as of the adsorption of liquid-infused colloidosomes at the liquid-fluid interface. The free energy of attachment of a composite ...

Interfaces are ubiquitous. They occur everywhere. They are the boundaries that separate distinct physical and chemical regions of matter. The bulk materials on adjacent sides of the interface can be chemically identical, as with a liquid water/vapor water interface, or they can be chemically different, as at ~t liquid/liquid interface such as hexadecane/water. All transfers of chemical species ...

The structure of the carbon dioxide-water interface was analyzed by X-ray diffraction and reflectivity at temperature and pressure conditions which allow the formation of gas hydrate. The water-gaseous CO2 and the water-liquid CO2 interface were examined. The two interfaces show a very different behavior with respect to the formation of gas hydrate. While the liquid-gas interface exhibits the f...

One way to determine the pH at the air/water interface with a confocal fluorescence microscope has been proposed. The relation between the pH at the air/water interface and that in a bulk solution has been formulated in connection with the adsorption equilibrium and the dissociation equilibrium of the dye adsorbed. Rhodamine B (RhB) is used as a surface-active fluorescent pH probe. The correcte...

Accumulation at the air-water interface of four bacterial strains with different hydrophobicities was studied. To exclude system influences, both a static batch system and a dynamic system involving rising bubbles were used. All bacteria accumulated at the air-water interface in both systems. Generally, attachment to the air-water interface increased with bacterial surface hydrophobicity. Accum...