We have developed a two-step filling process for the nano-reaction of ionic liquid in a tip-closed SWNT, where fullerenes are inserted at the end of the host SWNT as a plug to prevent the leakage of the confined ionic liquid during heat treatment.

We present an innovative wet-chemistry-assisted nanotube-substitution reaction approach for the highly efficient synthesis of boron- and nitrogen-codoped single-walled carbon nanotubes (B(x)C(y)N(z)-SWNTs) in bulk quantities. The as-synthesized ternary system B(x)C(y)N(z)-SWNTs are of high purity and quality and have fairly homogeneous B and N dopant concentrations. Electrical transport measure...

We present atomic-scale, video-rate environmental transmission electron microscopy and in situ time-resolved X-ray photoelectron spectroscopy of surface-bound catalytic chemical vapor deposition of single-walled carbon nanotubes and nanofibers. We observe that transition metal catalyst nanoparticles on SiOx support show crystalline lattice fringe contrast and high deformability before and durin...

Single-walled carbon nanotube ~SWNT! tips have been used to image nanostructures with high resolution. Studies of gold nanocrystal standards showed that SWNT tips provide a significant improvement in lateral resolution with respect to multi-walled nanotube tips and microfabricated Si tips. The nanotube tips were also used to resolve substructure within SWNTs deposited on surfaces. These results...

In this work the synthesis of polyaniline/chitosan/functionalized single- walled carbon nanotube nanocomposite is carried out. For this purpose single -walled carbon nanotubes were reacted with thionyl chloride to change the hydroxyl to acyl chloride groups for improving the react ability. In other step, aniline monomers and chitosan were polymerized in the presence of Iron (III) chloride to sy...

This paper proposes a two-dimensional elastic shell model to characterize the deformation of single-walled carbon nanotubes using the in-plane rigidity, Poisson ratio, bending rigidity and off-plane torsion rigidity as independent elastic constants. It was found that the off-plane torsion rigidity of a single-walled carbon nanotube is not zero due to the off-plane change in the π-orbital electr...

In the processes that are used to produce single-walled nanotubes (electric arc, laser ablation, and chemical vapor deposition), the typical lengths of tangled nanotube bundles reach several tens of micrometers. We report that long nanotube strands, up to several centimeters in length, consisting of aligned single-walled nanotubes can be synthesized by the catalytic pyrolysis of n-hexane with a...

The use of mixed catalysts for the high-yield production of single-walled carbon nanotubes is well-known. The mechanisms behind the improved yield are poorly understood. In this study, we systematically explore different catalyst combinations from Ni, Co, and Mo for the synthesis of carbon nanotubes via laser evaporation. Our findings reveal that the mixing of catalysts alters the catalyst clus...

A poly(acrylic acid)±surfactant±multi-walled carbon nanotube complex was prepared and characterized using transmission electron microscopy, scanning electron microscopy, wide-angle X-ray di€raction and small-angle X-ray di€raction. The complex was found to retain a lamellar structure, and helped micrometer-length multi-walled carbon nanotube dissolve in organic solvents. Its nonlinear optical p...

A continuum model is presented to study vdW interaction on buckling analysis of multi-walled walled carbon nanotube. In previous studies, only the vdW interaction between adjacent two layers was considered and the vdW interaction between the other two layers was neglected. The results show that the vdW interaction cofficients are dependent on the change of interlayer spacing and the radii of tu...