In this study, ionic liquid (IL) supported magnetic dispersive solid-phase microextraction was developed and a systematic investigation was conducted on imidazolium ILs for their extraction performance. This nano-based pretreatment procedure was then applied for the determination of acaricides in fruit juice samples for the first time. A feature of this technique is that the commonly laborious ...

Direct analysis of samples, regardless their origin, is desirable although for the majority of cases unfeasible on account of the complexity of the sample matrix, inadequate concentration of the target analytes, or even incompatibility with the detector. In these cases, a sample pretreatment step is required for interference removal and analytes separation/preconcentration. Despite valuable adv...

an air–assisted liquid–liquid microextraction method for the extraction and preconcentration of trace amounts of some synthetic phenolic antioxidants in biological fluids followed by their determination by gas chromatography–flame ionization detection has been reported. in this method the target analytes are extracted into a few microliters of carbon tetrachloride (extraction solvent) from an a...

This work describes the development of an HPLC-FLD methodology for separation five fluoroquinolones (ciprofloxacin, enrofloxacin, sarafloxacin, norfloxacin and levofloxacin) followed by optimization DLLME process clean-up preconcentration enrofloxacin in samples seawater river water. The mobile phase used chromatographic consisted methanol: phosphate buffer (NaHPO4 H2O 0.04 M pH 3 with H3PO4 85...

Vortex-assisted liquid-liquid microextraction (VALLME) coupled with high-performance liquid chromatography (HPLC) is proposed here for the rapid determination of octanol-water partitioning coefficients (Kow). VALLME uses vortex agitation, a mild emulsification procedure, to disperse microvolumes of octanol in the aqueous phase thus increasing the interfacial contact area and ensuring faster par...

A simple and rapid vortex assisted ionic liquid based liquid-liquid microextraction technique (VALLME) was proposed for preconcentration of trace levels of cadmium. According to this method, the extraction solvent was dispersed into the aqueous samples by the assistance of vortex agitator. Cadmium preconcentration was mediated by chelation with the 8-hydroxyquinoline (oxine) reagent and an IL, ...