ab initio calculation at hf/6-31g* level of theory for geometry optimization and mp2/6-31g*//hf/6-31g* for a single point total energy calculation are reported for the important energyminimumconformations and transition-state geometries of of cyclodeca-1,2,3-triene (1). the mostfavorable conformation of 1 is a unsymmetrical twist-chair (1-tc) structure. degenerateinterconversion of 1-tc with it...

We propose an experimental method for investigating the kinematics of metal flow in twist extrusion (TE). The method is based on a theoretical model of the velocity field. The parameters of this model are determined to satisfy the observed flow-line for characteristic points of the specimen. The model incorporates two physical constraints: (1) metal flow is limited by the surface of the die; (2...

To cleave DNA, the single polypeptide restriction-modification enzyme LlaGI must communicate between a pair of indirectly repeated recognition sites. We demonstrate that this communication occurs by a 1-dimensional route, namely unidirectional dsDNA loop translocation rightward of the specific recognition sequence 5'-CTnGAyG-3' as written (where n is either A, G, C or T and y is either C or T)....

– The mean time between submission and acceptance was 1.4 months. Also, since January 2007, the journal has been published in its entirety in English, in digital format, and freely accessible without subscription through MEDLINE. This online access has been a complete success. For the immediate future we have proposed the fulfillment of the dream of many members: to finally have an impact facto...

Ab initio calculation at HF/6-31G* level of theory for geometry optimization and MP2/6-31G*//HF/6-31G* for a single point total energy calculation are reported for the important energyminimumconformations and transition-state geometries of of cyclodeca-1,2,3-triene (1). The mostfavorable conformation of 1 is a unsymmetrical twist-chair (1-TC) structure. Degenerateinterconversion of 1-TC with it...

background: metastasis is one the most leading cause of death from cancer. the chemokine receptor of cxcr4 has an important role in cell migration and cancer metastasis. additionally, metastasis is always associated with the process of epithelial-mesenchymal transition (emt). in this study the correlation between expression of cxcr4 and emt-tfs has been examined. methods: the expression of cxcr...

This study presents a comprehensive evaluation of the effects multi-channel spiral twist extrusion (MCSTE) processing on mechanical properties and structural evolution AA5083. The texture developed were mapped by electron backscatter diffraction (EBSD) for three successive passes compared with an as-annealed plate. An hardness tensile was presented correlated EBSD findings. displayed results re...

we used qcd factorization for the hadronic matrix elements to show that the existing data, in particular the branching ratios br ( ?j/?k) and br ( ?j/??), can be accounted for this approach. we analyzed the decay within the framework of qcd factorization. we have complete calculation of the relevant hard-scattering kernels for twist-2 and twist-3. we calculated this decays in a special scale ( ...