Thallium ions are transported to the interior of gallium-seamed pyrogallol[4]arene nanocapsules. In comparison to the capture of Cs ions, the extent of which depends on the type and position of the anion employed in the cesium salt, the enhanced strength of Tl···π vs Cs···π interactions facilitates permanent entrapment of Tl(+) ions on the capsule interior. "Stitching-up" the capsule seam with ...

We report the synthesis, characterization, and computational rationalization of the first trimetallic deltahedral Zintl ions. The novel nine-atom clusters were structurally characterized as dimers of [(Sn(6)Ge(2)Bi)(2)](4-) with Ge-Ge intercluster bonds. They are synthesized either by reacting bimetallic clusters (Sn(9-x)Ge(x))(4-) with BiPh(3) or by direct extraction from precursors with nomin...

A novel and ultrasensitive sandwich-type electrochemical immunosensor was designed for the quantitative detection of carcino-embryonic antigen (CEA). This immunosensor was developed by using the trimetallic NiAuPt nanoparticles on graphene nanosheets (NGs) nanosheets (NiAuPt-NGs) as excellent labels and β-cyclodextrin functionalized reduced graphene oxide nanosheets (CD-NGs) as the platform. Th...

In this study, we have successfully synthesized electrode materials containing Pt on modified graphite by electrodeposition method, such as: Pt/C, Pt-Au/C Pt-Pd/C, Pt-Ni/C, Pt-Ni-Au/C, Pt-Ni-Pd/C. The formation of coating the surface is demonstrated through SEM, EDS results. Synthetic are used as catalysts for hydrogen evolution reaction (HER). results show that Bimetallic composites exhibit hi...

Trimetallic Au–Pd–Pt nanoparticles have been supported on activated carbon by the sol-immobilisation method. They are found to be highly active and selective catalysts for the solvent-free aerobic oxidation of benzyl alcohol. The addition of Pt promotes the selectivity to the desired product benzaldehyde at the expense of toluene formation. Detailed aberration corrected STEM-XEDS analysis confi...

A pentacoordinate methylidene carbon atom was trapped in a neutral trimetallic aluminum core using naphthalene bis amidinate ligand. The resulting complex exhibits the shortest equatorial Al–C bond distance reported for Al 3 -(μ -CH 2 ) moieties.

Using 1,3-bis(chloroacetamido)propane (5) as the common intermediate, an efficient route is described to the stepwise syntheses of 1-thia-4,8-diazacyclodecane, [10]aneN2S (8), and the pentadentate macrobicycle 17-thia-1,4,8,11tetraazabicyclo[9,5,3]-nonadecane (11). During the investigation of the condensation of (5) with (8), with Li2CO3 used as a base the Li+ cation is carried over as the comp...

Sequential embedding of metal complexes 4?-(pyridin-4-yl)-2,2?:6?,2??-terpyridine to a surface-enhanced supports pre-functionalized with templating layer results in hetero-bimetallic (Os–Fe, Co–Fe) and hetero-trimetallic (Co–Os–Fe) monolayer materials.