نتایج جستجو برای: transannular interaction

تعداد نتایج: 565925  

Journal: :Organic & biomolecular chemistry 2011
Donald Craig Kiyohiko Funai Sophie J Gore Albert Kang Alexander V W Mayweg

Unsaturated eight-membered lactones undergo decarboxylative and non-decarboxylative transannular Ireland-Claisen rearrangement reactions, to give substituted vinylcyclobutanes. A formal synthesis of (±)-grandisol is described.

Journal: :Internal medicine 2009
Masaomi Chinushi Satoru Komura Hiroshi Furushima Yoshifusa Aizawa

Macro-reentrant ventricular tachycardia (VT) developed in a 20-year-old man, 17 years after surgical repair of tetralogy of Fallot. Activation mapping of the VT revealed its counterclockwise propagation around the right ventricle, and through a critical pathway between a transannular patch and the tricuspid annulus. This critical pathway was 6 cm long and contained myocardium with a normal ampl...

Journal: :European heart journal 1996
R D Mainwaring J J Lamberti J W Moore G F Billman T L Carter J C Nelson

Fluid retention is a common problem following transannular patch repair of tetralogy of Fallot. The present study was undertaken to evaluate whether humoral substances may contribute to this process. Patients undergoing tetralogy of Fallot repair using a transannular patch technique were compared to patients undergoing simple ventricular septal defect repair. Hormone levels were determined by r...

Journal: :Organic & biomolecular chemistry 2011
Mudassar Iqbal Richard J G Black Joby Winn Andrew T Reeder Alexander J Blake Paul A Clarke

A series of diverse natural product-like structures have been synthesised by the use of a number of novel transannulation reactions across a cyclononene ring. Transannular cyclisations through oxygen functionality have generated a number of bicyclo[5.3.1]systems containing bridged cyclic ethers and bicyclo[5.2.2]lactones, as well as a tetrahydrofuran-containing bridged analogue of hexacyclinic ...

Journal: :Circulation. Cardiovascular interventions 2016
Rosanne C Schoonbeek Satoshi Takebayashi Chikashi Aoki Toru Shimaoka Matthew A Harris Gregory L Fu Timothy S Kim Yoav Dori Jeremy McGarvey Harold Litt Wobbe Bouma Gerald Zsido Andrew C Glatz Jonathan J Rome Robert C Gorman Joseph H Gorman Matthew J Gillespie

BACKGROUND Pulmonary insufficiency is the nexus of late morbidity and mortality after transannular patch repair of tetralogy of Fallot. This study aimed to establish the feasibility of implantation of the novel Medtronic Harmony transcatheter pulmonary valve (hTPV) and to assess its effect on pulmonary insufficiency and ventricular function in an ovine model of chronic postoperative pulmonary i...

Journal: :Revista espanola de cardiologia 2010
Juan-Miguel Gil-Jaurena Manuel Ferreiros Rafael Castillo Lourdes Conejo Victorio Cuenca Juan-Ignacio Zabala

INTRODUCTION AND OBJECTIVES To report on our initial experience with the implantation of a pulmonary valve using Nunn's technique in association with a transannular patch for the complete repair of the tetralogy of Fallot. METHODS In total, 21 patients were treated between September 2008 and February 2010. Their ages ranged from 7 months to 15 years (median 12 months) and weights from 6.8 kg ...

Journal: :Chemical communications 2010
Donald Craig Sophie J Gore Mark I Lansdell Simon E Lewis Alexander V W Mayweg Andrew J P White

Unsaturated epsilon-lactones bearing an alpha-arylsulfonyl or alpha-arylsulfoximinyl substituent undergo stereoselective transannular, decarboxylative Claisen rearrangement to give substituted vinylcyclopropanes.

2004
Pierre Deslongchamps

Various aspects of the transannular Diels-Alder reaction are examined in order to eventually develop a general method for the synthesis of a large variety of polycyclic compounds related to the diterpenes, mterpenes and steroids. Emphasis is made on the control of the relative and absolute configuration of the polycyclic products. Preliminary work towards the synthesis of some specific target n...

Journal: :Dalton transactions 2015
Lauren E Longobardi Tayseer Mahdi Douglas W Stephan

The stoichiometric reaction of para-methoxyanilines and B(C6F5)3 under H2 results in reduction of the N-bound phenyl ring(s), and subsequent transannular ring closure with elimination of methanol, affording the respective 7-azabicyclo[2.2.1]heptane derivatives.

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