Speciation of copper in the incineration waste heat boiler (HB) and the down stream electrostatic precipitator (EP) fly ashes during the flue gas cooling down (1123-->473 K) has been studied by X-ray absorption near edge structural (XANES) spectroscopy in the present work. Copper species such as Cu(OH)(2) (59-67%), CuCl(2) (5-12%), CuO (24-26%), and a small amount of CuS (3-4%) in fly ashes wer...

The present paper discusses sintered glass–ceramics with attractive appearance, which are obtained by vitrification of hazardous industrial wastes. The chemical durability of parent wastes and resulting glasses was characterised by toxic characteristics leaching procedure (TCLP). The crystallisation behaviour was evaluated by DTA and XRD, while the structure of materials was observed by optical...

Sequential extractions, metal uptake by Taraxacum officinale, Ruby’s physiologically based extraction test (PBET) and toxicity characteristic leaching procedure (TCLP), were used to assess the risk of Pb and Zn in contaminated soils, and to determine relationships among soil characteristics, heavy metals soil fractionation, bioavailability and leachability. Regression analysis using linear and ...

Jarosite released from zinc metal extraction process is hazardous in nature and its world wide disposal has become a major environmental concern. In this study, an attempt has been made to immobilise and recycle the jarosite released from Hindustan Zinc Limited, India, using CCRs, so called fly ash, and clay soil. Results revealed that the particle size of jarosite was finer than that of CCRs a...

background: the occurrence of heavy metals in the environment is of important concern due to their toxicity and health effects on humans, including cancer. because metals have been extensively used for centuries in commerce, environmental contamination is widespread; moreover, exposure to metals and metal compounds continues to be a significant public health problem. electroplating sludge conta...

Laboratory experiments and modeling studies were performed to investigate the redox transformations of arsenic and iron in water treatment sludge during aging, and to evaluate the impact of those transformations on the leachability of arsenic determined with the U.S. EPA toxicity characteristic leaching procedure (TCLP). When the backwash suspension samples collected from a California surface w...

A long-term field-scale demonstration project on the feasibility of using P to immobilize Pb in a Pb-contaminated urban soil was conducted. Phosphate was applied at an average rate of 3040 mg Pykg soil based on a PyPb molar ration of 4.0, with four treatments: T , no P application; T , H PO only; T , 1y2 H PO q1y2 CaH PO ; and T , 0 1 3 4 2 3 4 2 4 3 1y2 H PO q1y2 phosphate rock. Soil samples w...

A lightweight aggregate was produced by sintering the mixture of gold mine tailings, red mud, and limestone at 1150 ◦C. The physical (i.e., skid resistance, abrasion resistance, and bond strength) and environmental (i.e., leachability) feasibility of this aggregate was assessed to consider its potential use as a construction material for bicycle lanes. The skid resistance (British pendulum numb...

In the present work, thermal treatment was used to stabilize municipal solid waste incineration (MSWI) fly ash, which was considered hazardous waste. Toxicity characteristic leaching procedure (TCLP) results indicated that, after the thermal process, the leaching concentrations of Pb, Cu, and Zn decreased from 8.08 to 0.16 mg/L, 0.12 to 0.017 mg/L and 0.39 to 0.1 mg/L, respectively, which well ...