phosphoryl containing ligand tri-n-octylphosphine oxide (topo) in dichloromethane has been used as an extracting agent for tetravalent thorium and trivalent europium ions from their 1 m sodium nitrates. the equilibrium data reveal that both ions are extracted as the complexes at 1:3 metal/ligand ratio. the values of conditional extraction equilibrium constant (kex) show the superior extractive ...

Despite a major expansion of uranium-ligand multiple bond chemistry in recent years, analogous complexes involving other actinides (An) remain scarce. For thorium, under ambient conditions only a few multiple bonds to carbon, nitrogen, phosphorus and chalcogenides are reported, and none to arsenic are known; indeed only two complexes with thorium-arsenic single bonds have been structurally auth...

Measurements of absolute thorium abundances on the lunar surface are presented using both the highand low-altitude data taken with the Lunar Prospector Gamma-Ray Spectrometer. An analysis of the uncertainties shows that the measured uncertainties are < 0.5 μg/g and are close to the theoretical limit of Poisson statistics. Currently, the overall systematic uncertainties are likely dominated by v...

Anhydrous thorium tetrachloride complexes ThCl(4)(DME)(2), ThCl(4)(1,4-dioxane)(2), and ThCl(4)(THF)(3.5) have been easily accessed from inexpensive, commercially available reagents under mild conditions and serve as excellent precursors to a variety of thorium(iv) halide, alkoxide, amide and organometallic compounds.

It has long been known that thorium-232 is a fertile radioactive material that can produce energy in nuclear reactors for conversion to electricity. Thorium-232 is well suited to a variety of reactor types including molten fluoride salt designs, heavy water CANDU configurations, and helium-cooled TRISO-

Thirty-two years after injection of thorium dioxide (Thorotrast) for diagnostic x-ray studies in a female patient deposits were found by light microscopy in the liver macrophages (Kupffer cells). They were shown by electron microscopy to be located inside secondary lysosomes, and by autoradiography and x-ray microanalysis they were identified as thorium.

Bulky terphenolate ligands allow the synthesis of rare heteroleptic thorium chloride, and borohydride complexes; in the absence of donor solvents, the terphenolate ligands protect the metal ions through neutral Th-η(6)-arene interactions in a thorium bis(arene) sandwich motif.

background: decrease of economically accessible uranium resources motivates consideration of breeding of fertile elements such as thorium. material and method: thorium oxide fuel burn up calculation of a simulated research reactor cooled heavy water has been proposed in the present work using mcnpx 2.6 code. two 233u and 235u isotopes have been used as fissile element of thorium oxide fuel. 135...

Oxidation of a ~1000Å sputter-deposited thorium thin film at 150°C in 100ppm of flowing oxygen in argon produces the long-sought solid form of thorium monoxide. Changes in the scattering length density (SLD) distribution in the film over the 700 min experiment measured by in-situ, dynamic neutron reflectometry (NR) shows the densities, compositions and thickness of the various thorium oxides la...

The reactivity of thorium-phosphido and thorium-arsenido bonds was probed using tert-butyl isocyanide, (t)BuNC. Reaction of (C5Me5)2Th[E(H)R]2, E = P, As; R = 2,4,6-(i)Pr3C6H2, 2,4,6-Me3C6H2 with (t)BuNC affords the first phosphaazaallene and arsaazaallene moieties with an f-element.