here, we report the synthesis of a schiff-base mixed-ligand complex of cadmium(іі) in bulk and nano-scales via the precipitation and sonochemical methods, respectively. the complex formula is [cd(3-bpdh)(3-bpdb)cl2]n (1), where the ligands are 3-bpdh = 2,5-bis(3-pyridyl)-3,4-diaza-2,4-hexadiene and 3-bpdb = 1,4-bis(3-pyridyl)-2,3-diaza-1,3-butadiene. the structure of mixed-ligand complex (1) wa...

Thermolysis of a diazirine end group Br-functional PCL leads to carbene generation and subsequent hyperbranched polymers. Grafting hydrophilic PEG yields amphiphilic polymers which self-assemble into spherical core–shell nanoparticles.

The synthesis and characterization of a series of homologous tetranuclear complexes [((i)Pr3PCu)2(MR2)2(SCH2CH2S)2] (MR2 = GaMe2 (2), GaEt2 (3), Ga(i)Pr2 (4), Ga(n)Bu2 (5) and InMe2 (6), InEt2 (7), In(i)Pr2 (8), In(n)Bu2 (9)) and of related compounds [((i)Pr3PCu)3(MR2)(SCH2CH2S)2] (MR2 = GaMe2 (10), GaEt2 (11), Ga(i)Pr2 (12), Ga(n)Bu2 (13) and InMe2 (14), InEt2 (15), In(i)Pr2 (16), In(n)Bu2 (17...

The thermal decomposition of Nafion N117 membrane, a typical perfluorosulfonic acid membrane that is widely used in various chemical technologies, was investigated in this study. Structural identification of thermolysis products in water and methanol was performed using liquid chromatography-electrospray ionization-tandem mass spectrometry (LC/ESI-MS/MS). The fluoride release was studied using ...

Thermolysis of the 3,5-hexadienyl acrylates (a) proceeds via the transition state E in which the connecting chain adopts a boatlike conformation due to a preference for maintaining ester overlap to afford the products b with good diastereoselectivity.

AIMS A simple and rapid method (designated thermolysis) for extracting genomic DNA from bulk fungal strains was described. METHODS AND RESULTS In the thermolysis method, a few mycelia or yeast cells were first rinsed with pure water to remove potential PCR inhibitors and then incubated in a lysis buffer at 85 degrees C to break down cell walls and membranes. This method was used to extract ge...

Abstract Thermolysis of thiirane oxide leads to production highly reactive sulfur monoxide. The liberated SO can in turn be trapped with a diene scavenger forming dihydrothiophene oxide. Since the intermediate diatomic possesses triplet ground state, transfer proceed on two spin‐state surfaces. Here, we study competition between singlet concerted and stepwise diradical mechanisms utilizing M06‐...

Functionalized polymer nanoparticles react and store molecular oxygen for several weeks in the form of endoperoxides. On-demand controlled release of singlet oxygen by the particles is achieved by thermolysis.

A simple and general method is reported to tune the multicolour output of lanthanide-ion doped NaYF(4) upconversion nanoparticles within a given composition by controlling the reaction temperature in the thermolysis procedure.

Monodispersed Ag2Se nanocubes and faceted nanocrystals have been synthesized by hexadecylamine (HDA) induced thermolysis of [(PPh3)3Ag2(SeC{O}Ph)2] in a mixture of TOP (tri-n-octyl phosphine) and HDA in the temperature range 95-180 degrees C.