Very accurate thermodynamic potential functions are available for fluid water, ice, seawater and humid air covering wide ranges of temperature and pressure conditions. They permit the consistent computation of all equilibrium properties as, for example, required for coupled atmosphereocean models or the analysis of observational or experimental data. With the exception of humid air, these poten...

The realization that entanglement can affect macroscopic properties of bulk solid-state systems is a challenge in physics and Chemistry. Theoretical physicists often are considered the entanglement between nearest-neighbor (NN) spins and tried to find its characterizations in terms of macroscopic thermodynamics observables as magnetization and specific heat. Here, we focus on the entanglement b...

In recent years, increasing attention has been focused on the use ofhalogenated hydrocarbon mixtures as working fluids in vapor compressionrefrigeration systems, e.g. heat pumps. This paper discusses phase rules,applied to the equilibrium of the vapor and liquid states of such mixtures.Mixtures of ideal behavior, those that obey Raoult's law, and those withdeviations from th...

Based on the Tsallis entropy, the nonextensive thermodynamic properties are studied as a qdeformation of classical statistical results using only probabilistic methods and straightforward calculations. It is shown that the constant in the Tsallis entropy depends on the deformation parameter and must be redefined to recover the usual thermodynamic relations. The notions of variance and covarianc...

Mixing two immiscible liquids (such as oil and water) using emulsifier and energy inputs has been the matter of study for decades. In early 1890’s extensive work have been carried out on macroemulsions (i.e. oil dispersed in water in the form of fine droplets or vice versa) (Becher, 1977) and several theories and methods of their formation have been vastly explored (Lissant 1976 and 1984). Howe...

we have investigated the electronic structure and thermodynamic properties of supercell of the
-al2o3 by first-principles calculation in framework of density functional theory (dft) and full potential linearized augmented plane wave (fp-lapw) with generalized gradient approximation (gga) and by quasi-harmonic debye model. our calculated value for direct band gap of α-al2o3 is 7.2 ev which is v...

in this article, we have calculated some thermodynamic properties for a system consisting of singy ionized 3he atoms and their corresponding removed electrons by employing the second quantization method at finite temperature. to perform the calculations, we have considered the kinetic term, and coulomb interaction between the particles in our hamiltonian. the calculated properties are free ener...

In this article, we have calculated some thermodynamic properties for a system consisting of singy ionized 3He atoms and their corresponding removed electrons by employing the second quantization method at finite temperature. To perform the calculations, we have considered the kinetic term, and Coulomb interaction between the particles in our Hamiltonian. The calculated properties are free ener...

in this study some thermodynamic parameters including freezing point, boiling point and the vapor pressure of urmia lake salt water were investigated as some important environmentally monitored physicochemical properties of urmia lake. in this regard salt concentration is chiefly responsible for the modification of the thermodynamic properties of urmia lake water which affects its overall envir...