preparation of 2-chlorobenzonitrile, and benzonitrile are reported here from the corresponding 2-chlorobenzaldehyde and benzaldehyde by the reaction of ammonium hydroxide/vpo titania, vpo bulk (ammonium metavanadate) cucr catalyst/air system in methanol. all these catalysts showed better conversions with reasonable selectivity to aromatic. the results prove that bet surface area results show vp...

we explore electro-catalytic properties of a system consisting of platinum and palladium nanoparticles dispersed over a nanotubular self-organized tio2 matrix. these electrodes prepared by electroess and microemulsion of palladium and palladium nanoparticles on to tio2 nanotubes, respectively. titanium oxide nanotubes were fabricated by anodizing titanium foil in ethylene glycol (eg) fluoride-c...

a rhamnolipid–type biosurfactant production by pseudomonas aeruginosa mm1011 was studied in a miniaturized shaken bioreactor. the operational parameters, affecting the biosurfactant production in shaken bioreactors, such as shaking frequency (200, 250, 300 rpm), filling volume (50, 75, 100 ml), and aeration rate (0.2, 0.6, 1 vvm), were optimized using response surface methodology. the optimizat...

low density polyethylene films incorporating different types of organically modified nanoclays were prepared. physical, surface morphology and mechanical properties of the films were analyzed by x-ray diffraction pattern, scanning electron microscopy and tensile strength (ts) and length increase until fracture point (e) parameters, respectively. colony counting method was used to investigate an...

In this work, we develop a correlative model based on the surface tension data in order to calculate thermodynamic parameters, such as interaction energy between components (Uij), activity coefficients and etc. In the new approach, by using Li et al. (LWW) model, a three-parameter surface tension equation is derived for liquid mixtures. The surface tension data of 54 aqueous and 73 non-aqueous ...

Bacillus mojavensis PTCC 1696 (a member of Bacillus subtilis group) has been isolated from the Iranian oil field (Masjed-I Soleyman), to examine its ability to produce biosurfactant (lipopeptide type) [28]. The present study was designed to characterize the antibacterial activity of th...

Torulopsis petrophilum can synthesize either a glycolipid surfactant or a protein emulsifier depending on the substrate used. These compounds were not produced to facilitate the uptake of an insoluble carbon source. The glycolipids produced were identical to the mixture isolated from T. bombicola.

We report the synthesis of nitrogen-doped urchin-like rutile TiO2 nanostructure at room temperature without further heat treatment. The process was operated through hydrolysis of Ti(OC4H9)4 employing the direct amination of the product. The samples characterized by x-ray diffraction (XRD), scanning electron microscopy (SEM), Transmission electron microscopy (TEM), Raman spectroscopy and Brunaue...