Two novel system configurations were proposed for oxy-fuel natural gas turbine systems with integrated steam reforming and CO2 capture and separation. The steam reforming heat is obtained from the available turbine exhaust heat, and the produced syngas is used as fuel with oxygen as the oxidizer. Internal combustion is used, which allows a very high heat input temperature. Moreover, the turbine...

Steam reforming is one of the most important processes for producing hydrogen from hydrocarbon fuels such as LPG and has attracted much attention due to its high efficiency and economy. In this study, the LPG steam reforming reaction was investigated on nickel catalysts supported on four various zeolites (H-Y, Na-Y, HZSM5 and Ferrierite). The catalytic tests were performed in a tubular fixed be...

steam reforming integrated with oxidation of methanol was considered with numerical simulation. the parallel micro-channels with circular cross sections were used. because when the catalytic deposited inside the rectangular micro-channels, it fills up the edges. hence, the approximation of a cylindrical channel is appropriate. effect of this changing in cross section was considered and results ...

Steam reforming of light hydrocarbons provides a promising method for hydrogen production. Ni-based catalysts are so far the best and the most commonly used catalysts for steam reforming because of their acceptably high activity and significantly lower cost in comparison with alternative precious metal-based catalysts. However, nickel catalysts are susceptible to deactivation from the depositio...

The conversion of logistics fuels to hydrogen by steam reforming is attractive but poses great challenge since they contain sulfur up to about 3000 ppm leading to catalyst deactivation due to sulfur poisoning. In this paper, we report the fabrication of nominally doped nanoscale ceriasupported rhodium catalyst matrices for their performance evaluation in sulfur-laden fuel streams. Systematic st...

At present, the commercial production of hydrogen is essentially carried out by catalytic steam reforming of hydrocarbons: natural gas and naphtha. However, the instability of the prices of natural gas makes the use of other raw materials increasingly attractive. This research focuses on the development of a technology for producing hydrogen from alternative resources, specifically from two typ...

Novel micro-structured string-reactor designed as catalytically active wires placed in parallel into a tube was developed. The small diameter of the channels (∼100 m) leads to a short radial diffusion time, a narrow residence time distribution (RTD), and a low pressure drop. This reactor was applied for the oxidative steam-reforming of methanol (OSRM) to produce hydrogen in autothermal mode for...

methanol steam reforming plays a pivotal role to produce hydrogen for fuel cell systems in a low temperature range. to accomplish higher methanol conversion and lower co production, the reaction was catalyzed by cuznfe mixed oxides. various ratios of fe and cu/zn were coprecipitated in differential method to optimize the cuznfe structure. the sample containing 45cu50zn5fe (wt. %) revealed its m...

a micro-channel heat exchanger reactor with different micro-baffle shapes has been studied numerically. governing equations were solved base on the finite volume method with fluent software. in upper section, oxidation reaction of methanol was occurred and in lower section, steam reforming of methanol was done. two sections were separated with solid part which played as heat exchanger and trans...

In this study we developed LaNixAl1-xO3 perovskite systems using a sol-gelmethod (with propionic acid as solvent) to use in methane-reforming reactions for producing synthesis gas. To understand the roles of the nature of the precursor and calcination conditions on the formation of LaNixAl1-xO3, we carried out identifications using NMR, FT-IR, XRD, SEM, and TEM. The precursor struc...