The acidity constants of 4-(2-pyridylazo)resorcinol (PAR, Scheme 1) in binary mixtures of methanol–water at 25 ◦C and an ionic strength of 0.1 M have been determined spectrophotometrically. DATa ANalysis (DATAN) program applied for determination of acidity constants. As percent of methanol increases in solvent mixtures the pKa constants also increased. There is linear relationship between acidi...

A theoretical treatment of electron angular momentum relaxation in atoms induced by electric field fluctuations in a liquid solvent cage is presented. It is shown that in the case of weak interaction between solvent shell and a "target" atom the rate of transitions between the components of a Kramers doublet decreases sharply with the increase of adiabatic splitting between the terms of atomic ...

Solvation of small and large clusters are studied by simulation, considering a range of solvent-solute attractive energy strengths. Over a wide range of conditions, both for solvation in the Lennard-Jones liquid and in the SPC model of water, it is shown that the mean solvent density varies linearly with changes in solvent-solute adhesion or attractive energy strength. This behavior is understo...

We study the effects of two kinds of interactions in tubelike polymers and demonstrate that they result in the formation of secondary motifs. The first has an entropic origin and is a measure of the effective space available to the solvent. The second arises from solvophobic interactions of the solvent with the polymers and leads to an energy proportional to the contact surface between the tube...

The technique of short bed--continuous development chromatography has been utilized to increase the separation of glycosphingolipids on high performance thin-layer chromatography plates. The theoretical goal of increasing separation of bands by decreasing solvent strength was achieved within a practical time span as a result of the high solvent velocities in the short bed tank. Examples are giv...

objective: the purpose of the study was to evaluate the influence of adding nanofiller particles to a dentin bonding agent on resin-dentin bond strength. materials and methods: fifty-four human intact premolar teeth were divided in to 6 groups of nine. the teeth were ground on occlusal surfaces and polished with 320 and then 600 grit silicon carbide papers. an experimental bonding system based ...

Waterborne polymers, including waterborne polyurethanes (WPU), polyester dispersions (PED), and polyacrylate emulsions (PAE), are employed as environmentally friendly water-based coatings and adhesives. An efficient, fast, stable, and safe cross-linking strategy is always desirable to impart waterborne polymers with improved mechanical properties and water/solvent/thermal and abrasion resistanc...

Oral mucosa is an attractive region for the local and systemic application of many drugs. Oral mucoadhesive films are preferred for their prolonged time of residence, the improved bioavailability of the drug they contain, their painless application, their protection against lesions, and their nonirritating properties. This work was focused on preparation of nonmedicated carmellose-based films u...

Today concrete is most generally utilized development material in the world due to its strength and sturdiness properties. To attain good strength, curing of concrete is important so we introduce the concept of self-curing concrete rather than immersion or sprinkle curing to avoid water scarcity. It was observed that water solvent polymers can be utilized as a self-curing agent, i.e. polyethyle...

Objective(s): The aim of this study was to synthesis new dental nanocomposites reinforced with fabricated glass nanoparticles and compare two methods for fabrication and investigate the effect of this filler on mechanical properties. Materials and Methods: The glass nanoparticles were produced by wet milling process. The particle size and shape was achieved using PSA and SEM. Glass nanoparticle...