By ultrasonic spray deposition of precursors, conformal deposition on 3D surfaces of tungsten oxide (WO₃) negative electrode and amorphous lithium lanthanum titanium oxide (LLT) solid-electrolyte has been achieved as well as an all-solid-state half-cell. Electrochemical activity was achieved of the WO₃ layers, annealed at temperatures of 500 °C. Galvanostatic measurements show a volumetric capa...

This paper presents a numerical calculation of the evolution of the spatially resolved solid concentration in the two electrodes of a lithium-ion cell. The microscopic solid concentration is driven by the macroscopic Butler–Volmer current density distribution, which is consequently driven by the applied current through the boundary conditions. The resulting, mostly causal, implementation of the...

Chloride ion sensing is important in many fields such as clinical diagnosis, environmental monitoring and industrial applications. We have measured chloride ions at a carbon paste electrode (CPE) and at a CPE modified with solid AgNO₃, a solution of AgNO₃ and/or solid silver particles. Detection limits (3 S/N) for chloride ions were 100 μM, 100 μM and 10 μM for solid AgNO₃, solution of AgNO₃ an...

Here we construct mechanically flexible and optically transparent thin film solid state supercapacitors by assembling nano-engineered carbon electrodes, prepared in porous templates, with morphology of interconnected arrays of complex shapes and porosity. The highly textured graphitic films act as electrode and current collector and integrated with solid polymer electrolyte, function as thin fi...

electrode has been investigated as the electrode substrate for deposition of a thin membrane ion gating polymer called polypyrrole (PPy). The PPy membrane was successfully deposited and its surface morphology studied using scanning electron microscopy. Given the properties of the bucky gel electrode and its ability to conduct ions, this work establishes the first step towards a semi-solid ion-g...

Flexible all-solid-state supercapacitors have offered promising applications as novel energy storage devices based on their merits, such as small size, low cost, light weight and high wearability for high-performance portable electronics. However, one major challenge to make flexible all-solid-state supercapacitors depends on the improvement of electrode materials with higher electrical conduct...

This paper presents a numerical calculation of the evolution of the spatially-resolved solid concentration in the two electrodes of a lithium-ion cell. The microscopic solid concentration is driven by the macroscopic Butler Volmer current density distribution which is consequently driven by the applied current through the boundary conditions. The resulting, mostlycausal, implementation of the a...

A new approach to potentiometric sensing utilizing paper-based microfluidic sampling is studied in this work. A solid-contact ion-selective electrode and a solid-contact reference electrode are pressed against a filter paper into which the sample solution is absorbed. The filter paper acts simultaneously as a sampling unit and as a sample container during potentiometric sensing. The paper subst...

High-energy conversion electrodes undergo successive Li insertion and conversion during lithiation. A primary scientific obstacle to harnessing the potentially high lithium storage capabilities of conversion electrode materials has been the formation of insulating new phases throughout the conversion reactions. These new phases are chemically stable, and electrochemically irreversible if formed...

The possible orrgins of frequent deviations from the calculated and experimentally obtained values of the Warburg parameter of the Ag/AgI electrode are discussed. Following the considerations of possible conditions for classical Warburg impedance to appear in solid AgI, it is suggested that the overall Warburg impedance of the Ag/AgI electrode could be considered as the sum of the Warburg imped...