density-functional theory is used to investigate sulfur dioxide physisorption inside and outside of single-wall carbon nanotube of (5,0) and (5,5). this study is conducted at b3lyp/6-31g* level of theory. sulfur dioxide molecule is studied with axis oriented parallel or perpendicular to the nanotube wall. both internal and external adsorption on nanotubes is increased with the angle of interact...

Adsorption of sulfur dioxide on carbonaceous materials has been extensively studied (1-18). Activated carbon and activated carbon fibers have been found to be efficient adsorbents for the low temperature removal of SO2. It is believed that sulfur dioxide is adsorbed with two adsorption energies on activated carbons (3-12). The low energy, about 50 kJ/mol, corresponds to weak physical adsorption...

Sulphur dioxide (SO2), a known industrial pollutant and pulmonary irritant, is emitted to the atmosphere in excess of 120 Mt per annum. Great strides have been taken to reduce SO2 emissions, but with the growth of specifically China, and to a lesser extent India, it is on the rise again. The electrolysis of aqueous solutions of dissolved SO2 holds huge environmental potential in that SO2 is con...

Density-functional theory is used to investigate sulfur dioxide physisorption inside and outside of single-wall carbon nanotube of (5,0) and (5,5). This study is conducted at B3LYP/6-31G* level of theory. Sulfur dioxide molecule is studied with axis oriented parallel or perpendicular to the nanotube wall. Both internal and external adsorption on nanotubes is increased with the angle of interact...

A sulfur transfer agent in catalysts can effectively reduce the emission of SO2 with minimum adverse effects on the catalytic cracking ability of the primary catalyst. In this paper, the composition and performance of sulfur transfer agents with different oxidative active components (such as Cu, Fe, Ni, Co, Ba, Zn and Cr) were prepared by acid peptization technique and characterized by X-ray di...

ABSTRACT Platinum has been widely used as the catalyst of choice for production hydrogen in hybrid sulphur (HyS) cycle. In this cycle, water (H2O) and dioxide (SO2) react to form sulphuric acid hydrogen. However, surface reactivity platinum towards H2O SO2 is not yet fully understood, especially considering competitive adsorption that may occur on surface. study, we have carried out density fun...