Eight new Zn(II) coordination polymers based on flexible 1,4-di(1H-imidazol-1-yl)butane and different dicarboxylates, [Zn(dimb)(suc)·2DMF]n (1), [Zn(dimb)(mbda)·3H2O]n (2), [Zn(dimb)(adip)·DMF·2H2O]n (3), [Zn(dimb)(pma)·2.5H2O]n (4), [Zn2(dimb)(tha)2(H2O)]n (5), [Zn(dimb)(chda)·2H2O]n (6), [Zn(dimb)(obda)·DMF]n (7), [Zn(dimb)(tdga)·CH3OH]n (8) (dimb = 1,4-di(1H-imidazol-1-yl)butane, H2suc = suc...

The structure of the nonaaquayttrium (III) bromate, [Y(H2O)9](BrO3)3, at low temperature (100 K) has been studied by means of single-crystal X-ray diffraction. Crystallography shows a hexagonal unit cell, space group P63/mmc (No. 194) with Z = 2, a = b = 11.7104(11) Å, c = 6.6259(5) Å and V = 786.90(12) Å3 at 100 K. The hydra...

The integral mitochondrial membrane protein cytochrome c oxidase (ferrocytochrome-c:oxygen oxidoreductase, EC 1.9.3.1) was crystallized from solutions of the protein from bovine heart isolated as described earlier [Yoshikawa, S. & Caughey, W. S. (1982) J. Biol. Chem. 257, 412-420]. Crystallinity was demonstrated by x-ray diffraction. Microcrystals (tetragonal prisms, 0.02 mm in the largest dime...

The synthesis and single-crystal X-ray structure determination of the title compound (dinitrato) (1,4,8,11 -tetra-azaandecane) lead(II) is described. Crystals are monoclinic, P2 /ca= 10.271 (2)?,b= 13.524(4) ?,c= 11.298(6) ?,?=94.68(3),2=4,R,Rw, 0.036 and 0.041, respectively. The lead atom is eight-coordinate [Pb-N, 2.44 (2) - 2.55 (1)], [Pb-0,2.87 (1) - 3.06 (2)].

A new one-dimensional uranium(VI) coordination polymer, [UO2(μ-DMP)2(TMP)]n (1) (DMP is dimethyl phosphate and TMP is trimethyl phosphate), was prepared from the reaction of UO2(NO3)2.6H2O and TMP in in THF (THF is tetrahydrofuran) as a solvent. Suitable crystals of this complex for crystal structure determination were obtained by slow evaporation of the produced yellow solution at room tempera...

A new two-dimensional manganese(II) coordination polymer, [Mn(μ-DEP)(μ-Cl)(H2O)2]n (1) (DEP is diethyl phosphate), was prepared from the reaction of MnCl2.4H2O and TEP (TEP is triethyl phosphate) ligand in mixture of H2O/CH3OH (1:10) at 40 °C. Suitable crystals of this complex for crystal structure determination were obtained by slow evaporation of the produced colorless solution at room temper...

a novel complex of cadmium (ii) [cdl0.5(no3)(h2o)](1), l= n,n-bis (o-hydroxyacetophenone) ethylene diamine, have been synthesized as single crystal and nano size. compound 1 in nano size was obtained under sonochemical irradiation and has been characterized by ir, 1hnmr spectroscopy, x-ray powder diffraction (xrd) and scanning electron microscopy (sem). the gray single crystal of compound 1 has...