Single-crystal platinum nanorods with high aspect ratios and tunable length were fabricated on a large scale by a glycol-assisted one-step vacuum impregnation method, using mesoporous inorganic silica SBA-15 as the host.

in this research, different alcohols and phenols are subjected to the reaction with hmds in the presence of ionic liquid and silica-supported catalysts. silylation was accomplished under mild reaction conditions at room temperature in short reaction times and good to excellent yields.

an efficient synthesis of polyhydroquinoline derivatives is achieved via hantzsch condensation reaction between aldehydes, dimedone, ethyl acetoacetate and ammonium acetate in the presence of catalytic amount of sfhs in ethanol. this method gives remarkable advantages such as shorter reaction time, simple workup procedure and good to excellent yields. furthermore the catalyst can be recovered c...

The increasing use of automobile catalysts leads to the emission of the platinum-group elements (PGE), mainly platinum, but also rhodium and palladium into the environment. In environmental samples, the low concentration of platinum together with the high concentration of interfering matrix components often requires a preconcentration/enrichment step combined with a matrix-separation. The metho...

Metallodielectric nanostructured core−shell− shell particles are particularly desirable for enabling novel types of optical components, including narrow-band absorbers, narrow-band photodetectors, and thermal emitters, as well as new types of sensors and catalysts. Here, we present a facile approach for the preparation of submicron SiO2@Pt@SiO2 core−shell−shell particles. As shown by transmissi...

We report on the endocytosis and the time-dependent enhanced cytotoxicity of anticancer platinum drugs when the drugs are combined with (or loaded into) one of the two most common types of mesoporous silica materials, MCM-41 or SBA-15. The anticancer drug cisplatin and its isomer transplatin, when loaded on MCM-41 and SBA-15 microparticles, were less cytotoxic to leukemia cells than the drugs a...