Time-resolved anisotropy decays of a fluorescent cationic solute, rhodamine 6G (R6G), in Ludox sols were measured to characterize the extent of the ionic binding of the probe to silica particles after modification of the surface with neutral or cationic silane coupling agents. The anisotropy decays provided direct evidence for distribution of the dye between the aqueous solution (picosecond dec...

Silica nanoparticles with a narrow particle size distribution and controlled diameters of 10-20 nm are synthesized via hydrolysis and hydrothermal aging of tetraethylorthosilicate in an aqueous L-lysine solution. Cryo-transmission electron microscopy (cryo-TEM) reveals that the silica nanoparticles assemble to form close-packed nanoparticle crystals over short length scales on carbon-coated gri...

Copyright 2012 KIEEME. All rights reserved. This is an open-access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/by-nc/3.0) which permits unrestricted noncommercial use, distribution, and reproduction in any medium, provided the original work is properly cited. Effect of Silica Content on the Dielectric Prope...

The current essay analyzes the anti-corrosion properties of epoxy primers including anti-corrosion pigment calcium hydrogen orthophosphate and hydrophobic nano silica with various percentages optimized by Taguchi experimental design. The impact of influential factors such as the percentage of anti-corrosion pigments, percentage of nano silica and pigment to binder ratio on anti-corrosion proper...

Hierarchically structured membranes composed of mesoporous silica embedded inside the channels of anodic alumina (MS-AAM) were synthesized using the aspiration method. Ethanol is shown to have a significant effect on the type and organization of the mesoporous silica phase. Detailed textural analysis revealed that the pore size distribution of the mesoporous silica narrows and the degree of ord...

We show a simple method to visualize the morphology of water adsorbed within the pore network of colloidal crystals made of submicrometer silica spheres. Water is replicated into silica by modified silicon tetrachloride hydrolysation under standard ambient conditions, making it visible to standard electronic microscopy and thus allowing one to discern the original water distribution. Different ...

A novel confined-space synthesis method has been developed to synthesize zeolite nanocrystals. Colloidal silica nanoparticles serving as the silica source as well as the hard template were embedded in the mesoporous carbon via in situ polymerization of furfuryl alcohol (FA) in the presence of tri-block copolymer (Pluronic P123), and then reacted with an alkaline aqueous solution (Na2O-Al2O3-H2O...

In this work, SiO2 –ZrO2 mixed oxides was prepared by the polymeric sol–gel route. The characterization of pore structure, which determines the permeation process of membrane, is of great importance. So far, most investigations have focused on such pore structure as specific surface area and pore size distribution, but the surface fractal, the important parameter reflecting the roughness of por...

A significantly soft and tough nanocomposite gel was realized by a novel network formed using cyclodextrin-based polyrotaxanes. Covalent bond formation between the cyclic components of polyrotaxanes and the surface of silica nanoparticles (15 nm diameter) resulted in an infinite network structure without direct bonds between the main chain polymer and the silica. Small-angle X-ray scattering re...