Dye-sensitized solar cells are a promising alternative to traditional inorganic semiconductor-based solar cells. Here we report an open-circuit voltage of over 1,000 mV in mesoscopic dye-sensitized solar cells incorporating a molecularly engineered cobalt complex as redox mediator. Cobalt complexes have negligible absorption in the visible region of the solar spectrum, and their redox propertie...

Oxide nanocrystallite aggregates are candidates for use in dye-sensitized solar cells. The aggregates are of submicron size, formed by nano-sized crystallites and, therefore, able to offer both a large specific surface area and desirable size comparable to the wavelength of light. While used for a photoelectrode in a dye-sensitized solar cell, the aggregates can be designed to generate effectiv...

Semiconductor sensitized solar cells, a promising candidate for next-generation photovoltaics, have seen notable progress using 0-D quantum dots as light harvesting materials. Integration of higher-dimensional nanostructures and their multi-composition variants into sensitized solar cells is, however, still not fully investigated despite their unique features potentially beneficial for improvin...

A zinc phthalocyanine (ZnPc) derivative (Zn-tri-PcNc-8) containing tri-benzonaphtho-condensed porphyrazine with one carboxylic and six diphenylphenoxy peripheral substitutions was designed and synthesized as a sensitizer for dye-sensitized solar cells (DSSCs). For the purpose of extending the absorption spectra while minimizing the formation of ZnPc molecular aggregates, bulky 2,6-diphenylpheno...

ground state geometries have been computed using density functional theory (dft) at b3lyp/6-31g(d,p) level of theory. the excitation energies and spectroscopic parameters have been computed using long range corrected (lc) hybrid functional by time dependent density functional theory (tddft) with lc-blyp level of theory. the polarizable continuum model (pcm) has been used for evaluating bulk sol...

The dye-sensitized solar cells (DSC) provides a technically and economically credible alternative concept to present day p–n junction photovoltaic devices. In contrast to the conventional systems where the semiconductor assume both the task of light absorption and charge carrier transport the two functions are separated here. Light is absorbed by a sensitizer, which is anchored to the surface o...

A pyrene photoluminescent layer is coated on the front side of a dye-sensitized solar cell to enhance the power conversion efficiency. The power conversion efficiency of the dye-sensitized solar cell coated with a pyrene photoluminescent layer improves from 9.12 ± 0.06% to 10.30 ± 0.11% (an improvement of 12.94%).

Dye sensitized solar cell (DSSC) is the only solar cell that can offer both the flexibility and transparency. Its efficiency is comparable to amorphous silicon solar cells but with a much lower cost. This review not only covers the fundamentals of DSSC but also the related cutting-edge research and its development for industrial applications. Most recent research topics on DSSC, for example, ap...

As a relatively new class of photovoltaic devices with a photoelectrochemical system consisting of a dye-sensitized semiconductor film and an electrolyte, dye-sensitized solar cells (DSSCs) have been regarded as a promising alternative to conventional solid-state semiconductor solar cells. They are relatively cost-effective, are easy to manufacture, and can be readily shaped with flexible subst...