Electronic self-decoupling of an organic chromophore from a metal substrate is achieved using a naphtalenediimide cyclophane to spatially separate one chromophore unit of the cyclophane from the substrate. Observations of vibronic excitations in scanning tunneling spectra demonstrate the success of this approach. These excitations contribute a significant part of the tunneling current and give ...

• A submitted manuscript is the author's version of the article upon submission and before peer-review. There can be important differences between the submitted version and the official published version of record. People interested in the research are advised to contact the author for the final version of the publication, or visit the DOI to the publisher's website. • The final author version ...

Reproducible fabrication of Scanning Tunneling Microscope tips is carried out following an electrochemical procedure widely reported. Tips are made from 0.5 diameter tungsten wire. Controlling fabrication parameters (immersion in the electrochemical solution, current-voltage ranges, duration of the process, among others) we achieve aspect ratios of 0.68 and tip radii of 330 nm in the best case....

We present a theory for tunneling between a real surface and a model probe tip, applicable to the recently developed "scanning tunneling microscope." The tunneling current is found to be proportional to the local density of states of the surface, at the position of the tip. The effective lateral resolution is related to the tip radius R and the vacuum gap distance d approximately as [(2 A)(R +d...

We present the design and performance of an active mechanical noise cancellation scanning tunneling microscope (STM). This system features two key parts: a "twin-tip" scanner and an active mechanical noise cancellation algorithm. The twin-tip scanner functions as two independent STMs which share nearly the same mechanical transfer function, allowing both STMs to sense nearly identical backgroun...

We present the first scanning tunneling spectroscopy study of single-crystalline boron-doped diamond. The measurements were performed below 100 mK with a low temperature scanning tunneling microscope. The tunneling density of states displays a clear superconducting gap. The temperature evolution of the order parameter follows the weak-coupling BCS law with Delta(0)/kBTc approximately 1.74. Vort...