Department of Chemistry, Kongunadu Arts and Science College, Coimbatore – 641029, India Post Graduate and Research Department of Chemistry, Sri Ramakrishna Mission Vidyalaya College of Arts and Science, Coimbatore – 641020, India. ABSTRACT: Six new organosoluble ruthenium(II) complexes bearing dibasic tetradentate Schiff base ligands of the general formula [Ru(CO)(PPh3)(L)] (where L = dibasic t...

II 1 A group of five new ruthenium(II) bipyridine heterochelates of the type [Ru (bpy) L] 1a–1e have been synthesized (bpy52,292 bipyridine; L5anionic form of the thiol-based imine ligands, HS–C H N=C(H)C H (R) (R5OMe, Me, H, Cl, NO ). The complexes 6 4 6 4 2 1a21e are 1:1 conducting and diamagnetic. The complexes 1a21e exhibit strong MLCT transitions in the visible region and intra-ligand tran...

Photocatalysis. In their Communication (e202304474), Markus R. Heinrich et al. demonstrate the linkage of ruthenium photocatalysis with chemiluminescence read-out from a 1,2-dioxetane. The ruthenium-dioxetane system was shown to be useful for quantification optical input by inverse correlation output.

Ruthenium(III) chloride-catalyzed acylation of a variety of alcohols, phenols, and thiols was achieved in high yields under mild conditions (room temperature) in the ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate ([bmim][PF(6)]). The ionic liquid and ruthenium catalyst can be recycled at least 10 times. Our system not only solves the basic problem of ruthenium catalyst reuse, but ...

Bismuth vanadate (BiVO(4)), which is a visible-light responsive heterogeneous photocatalyst, was combined with homogeneous ruthenium complexes to increase the overall photocatalytic reactivity for water oxidation with a one-electron oxidant, [Co(III)(NH(3))(5)Cl](2+). Photoinduced electron transfer from the excited state of ruthenium(II) complexes to [Co(III)(NH(3))(5)Cl](2+) affords ruthenium(...

A terpyridine ruthenium (II) complex containing a substituted and an unsubstituted terpyridine ligand was synthesized, and its luminescence properties were studied in a solid-state single-layer light-emitting electrochemical cell. The obtained devices emitted light of a very deep red color (CIE, x = 0.717 y = 0.282) at low external applied bias. It is the first example of an electroluminescence...

Reaction of three phenolate ligands, viz. 2,4,6-tribromophenol (HL, where H stands for the phenolic proton), 2-nitrophenol (HL) and 2,4,6-trinitrophenol (HLO), with [Ru(PPh3)3Cl2] in a 2:1 molar ratio in the presence of a base gives complexes of type [Ru(PPh3)2(L)2] (L=L , L and L). The 2,4,6-tribromophenolate ligand (L) binds to ruthenium as a bidentate O,Br-donor, while the 2-nitrophenolate l...

In the title complex, [RuSn(2)(C(10)H(14))Cl(6)(C(6)H(15)O(3)P)], the Ru-Sn bond lengths [2.5619 (3) and 2.5669 (3) Å] are about 0.3 Å shorter than the sum of the covalent Ru and Sn radii (1.46 + 1.39 = 2.85 Å), in line with other structurally characterized arene ruthenium trichlorido-stannyl derivatives. The Ru(II) atom is surrounded by a para-cymene, a triethylphosphite and two trichloridosta...

Highly enantioselective hydrogenation of various N-Boc-indoles proceeded successfully in the presence of the ruthenium complex generated from an appropriate ruthenium precursor and a trans-chelate chiral bisphosphine PhTRAP. Various 2- or 3-substituted indoles were converted into chiral indolines with high enantiomeric excesses (up to 95% ee). The PhTRAP-ruthenium catalyst was able to promote t...