نتایج جستجو برای: rotational state

تعداد نتایج: 883857  

2008
G. S. Sharov

For the closed string carrying 2 or 3 point-like masses the stability problem for central and linear rotational states is considered. This problem is important for applications of these model to describing baryons, glueballs or other exotic hadrons. The linear rotational state correspond to an uniform rotation of the system with rectilinear string segments, connecting massive points. The state ...

Journal: :Soft matter 2015
Vasileios Prymidis Harmen Sielcken Laura Filion

We study the self-assembly of a system of self-propelled, Lennard-Jones particles using Brownian dynamics simulations. We examine the state diagrams of the system for different rotational diffusion coefficients of the self-propelled motion of the particles. For fast rotational diffusion, the state diagram exhibits a strong similarity to that of the equilibrium Lennard-Jones fluid. As we decreas...

Journal: :The Journal of chemical physics 2010
David R Farley

A model has been developed to calculate the ground state rotational populations of homonuclear diatomic molecules in kinetic gases, including the effects of electron-impact excitation, wall collisions, and gas feed rate. The equations are exact within the accuracy of the cross sections used and of the assumed equilibrating effect of wall collisions. It is found that the inflow of feed gas and e...

Journal: :Science 2011
Christian Schröter Kyriaki Kosma Thomas Schultz

Rotational spectra have traditionally been measured without a concurrent means of differentiating the molecular constituents of the sample. Here, we present an all-optical multipulse experiment that allows the correlated measurement of rotational and mass or photoelectron spectra by combining Fourier transform rotational coherence spectroscopy with resonance-enhanced multiphoton ionization. We ...

Journal: :Physical review letters 2011
E J Salumbides G D Dickenson T I Ivanov W Ubachs

Quantum electrodynamic effects have been systematically tested in the progression of rotational quantum states in the X 1Σ(g)(+), v=0 vibronic ground state of molecular hydrogen. High-precision Doppler-free spectroscopy of the EF 1Σ(g)(+)-X 1Σ(g)(+) (0,0) band was performed with 0.005  cm(-1) accuracy on rotationally hot H2 (with rotational quantum states J up to 16). QED and relativistic contr...

Journal: :The journal of physical chemistry. A 2008
Wei Zhou Hui Wu Terrence J Udovic John J Rush Taner Yildirim

Using neutron inelastic scattering and diffraction, we have studied the quantum methyl rotation in zeolitic imidazolate framework-8 (ZIF-8: Zn(MeIM)(2), MeIM = 2-methylimidazolate). The rotational potential for the CH(3) groups in ZIF-8 is shown to be primarily 3-fold in character. The ground-state tunneling transitions at 1.4 K of 334 +/- 1 mueV for CH(3) groups in hydrogenated ZIF-8 (H-ZIF-8)...

Journal: :Physical chemistry chemical physics : PCCP 2009
Iftach Nevo Lotte Holmegaard Jens H Nielsen Jonas L Hansen Henrik Stapelfeldt Frank Filsinger Gerard Meijer Jochen Küpper

A strong inhomogeneous static electric field is used to spatially disperse a rotationally cold supersonic beam of 2,6-difluoroiodobenzene molecules according to their rotational quantum state. The molecules in the lowest-lying rotational states are selected and used as targets for 3-dimensional alignment and orientation. The alignment is induced in the adiabatic regime with an elliptically pola...

2001
Xue Qing Tan James M. Williamson

High-resolution electronic excitation spectra of the 0: and the 9; bands of the near-UV electronic transition of the ethoxy radical have been recorded. The ethoxy radical was produced in a free-jet expansion by photodissociation of ethyl nitrite (CzHsONO). Both spectra have a linewidth of about 400 MHz. A complete rotational analysis of the spectrum indicates that the electronic transition of e...

1996
K. Yokoyama W. C. Lineberger K. M. T. Yamada

A breakdown of the standard Watson-type rotational Hamiltonian was suggested for a molecule with H2XYZ structure [Š. Urban and K. M. T. Yamada, J. Mol. Spectrosc. 160, 279–288 (1993)] . This breakdown is due to a near-resonant interaction between the ground state rotational levels and rotational levels in an excited vibrational state. This interaction has been observed in the excited electronic...

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