In the present study, advanced oxidation treatment, UV/ was applied to decolourisation of Acid Orange 8 (AO8). The UV radiation was carried out with a 15 W low-pressure mercury lamp. Kinetic model for the decolourisation of the dye was developed based on experimental results and known chemical and photochemical reactions. The observed kinetic reaction constant was determined and correlated as a...

Kinetic parameters of the ammonolysis reaction of dichloroethane in nonaqueous media are studied and the optimum reaction conditions are reported. A suitable reactor for running the reaction under high pressure in the range of 50 to 500 °C is designed. Kinetic behaviours of the system is studied and other reaction parameters such as rate constant, kinetic order, and activation energy are de...

in the present work, the extraction of zinc from a sphalerite concentrate using sodium nitrate as an oxidant in a sulfuric acid solution was investigated. the effective parameters such as the temperature, sulfuric acid and sodium nitrite concentrations, stirring speed, particle size, and solid/liquid (s/l) ratio were analyzed. the dissolution rate increased with increase in the sulfuric acid an...

Kinetic study of free fatty acids (FFAs) esterification for biodiesel production from palm fatty acid distillate (PFAD) using sulfated zirconia (S-ZrO2) prepared by solvent-free method calcined at low temperature as the heterogeneous catalyst was studied. The reaction was performed in a batch-stirred reactor at the different temperature to obtain the kinetic data. The effect of reaction conditi...

the steel slag is the main by-product of steel industry. the aim of this study using the steel slag as a low-cost absorbent in order to remove cadmium pollutant from industrial wastewater. some factors that affect the process of cadmium removal by steel slag such as ph, contact time, absorbent dosage and cadmium initial concentration has been studied. standard solution of synthetic wastewater i...

The kinetics and mechanism of the reaction between benzaldehyde 1, malononitrile 2 and dimedone 3 in a mixture of ethanol and water as solvents in the presence of fructose as a biodegradable catalyst has been studied by the spectroscopic method (UV-Vis spectrophotometry method). The influence of various parameters (temperature, solvent and concentration) was studied on the reaction by means of ...

In this paper, conventional SAPO-34 and Cerium Hierarchical SAPO-34 zeolites are synthesized using a hydrothermal method for methanol-to-propylene (MTP) reaction. The Ce-H-SAPO-34 catalyst shows a slightly larger crystal size, bimodal pore size distribution (microporous and mesoporous) and lower surface acidity compared to conventional SAPO-34 catalysts. According to these physicochemical prope...

abstract in this work, the dry reforming of methane was studied using a corona and glow discharge plasma microreactors. a chemical kinetic model was developed to understand the reaction better. the modelization allowed prediction of the reactants conversion according to the energy transfer to the gas (p×τ). the β value is trait of the energy cost, whatever this value was leeser indicated better...

The olefins polymerization process in a slurry reactor is discussed. The reaction rate dynamics was analyzed and the contributions of feed flow, gas-liquid mass transfer, polymerization reaction, and catalyst deactivation were estimated. The propylene solubility in a solvent mixture “heptane” was calculated using Soave-Redlich-Kwong equation of state. These data were then approximated by Henry-...