نتایج جستجو برای: quantum chemistry

تعداد نتایج: 394832  

2009
A. Görling

Orbitals, on the one hand, are often considered as auxiliary quantities without physical meaning for various reasons. Slater determinants, e.g., Hartree-Fock or Kohn-Sham determinants, are invariant with respect to unitary transformations of the occupied orbitals. Within densityfunctional theory (DFT) orbitals frequently are considered as quantities that merely generate the electron density but...

Journal: :Nature Physics 2012

Journal: :International Journal of Quantum Chemistry 2012

Journal: :International Journal of Quantum Chemistry 1967

2013
Sam P. de Visser

In the past few decades, computational resources have become more powerful every year and in addition methodology development has led to much more efficient techniques through parallelization of the calculations and the advent of density functional theory. These reasons make it possible for computational quantum chemists to work on relatively large chemical systems with a total number of atoms ...

Journal: :Nuclear Physics B 2004

Journal: :Nature Computational Science 2021

2014
M.-H. Yung J. Casanova A. Mezzacapo J. McClean L. Lamata A. Aspuru-Guzik E. Solano

Over the last few decades, quantum chemistry has progressed through the development of computational methods based on modern digital computers. However, these methods can hardly fulfill the exponentially-growing resource requirements when applied to large quantum systems. As pointed out by Feynman, this restriction is intrinsic to all computational models based on classical physics. Recently, t...

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