Coupling an infrared (IR) camera to a freeze dryer for on-line monitoring of freeze-drying cycles is described for the first time. Normally, product temperature is measured using a few invasive Pt-100 probes, resulting in poor spatial resolution. To overcome this, an IR camera was placed on a process-scale freeze dryer. Imaging took place every 120 s through a Germanium window comprising 30,000...

We investigated working memory updating performance in younger and older adults before, during, and after 100-day practice. Performance to presentation time (PT) relation was fitted to a negatively accelerated logistic function. Relative to younger adults, older adults showed lower asymptotes at pretest and posttest, and shallower slopes at pretest. Older adults practicing the task with fast PT...

The interaction and reactivity of n-octane adsorbed on the (1×1) and (5×20) surfaces of Pt(100) have been examined by reflection-absorption infrared (RAIRS), temperature-programmed reaction (TPRS), andAuger electron (AES) spectroscopies andby low-energy electrondiffraction (LEED). A strongC-H‚‚‚M interaction between the adsorbate and the metal was present on both surfaces at 100 K, as evidenced...

The thermally activated formation of nanoscale CoPt alloys was investigated, after deposition of self-assembled Co nanoparticles on textured Pt(111) and epitaxial Pt(100) films on MgO(100) and SrTiO(3)(100) substrates, respectively. For this purpose, metallic Co nanoparticles (diameter 7 nm) were prepared with a spacing of 100 nm by deposition of precursor-loaded reverse micelles, subsequent pl...

Objectives • Further improve the new catalyst consisting of a submonolayer of Pt on carbon-supported Ru nanoparticles (1%Pt/10%Ru/C) to come close to the DOE’s 2010 target of 100 μg/cm2 noble metal loading. • Further elucidate the inhibition mechanism of CO on H2 oxidation on Pt. • Reduce Ru loadings in Pt-Ru electrocatalysts. • Explore monolayer-level-supported Pt electrocatalysts for O2 reduc...