Versatile polyelectrolytes with tunable physical properties have the potential to be transformative in applications such as energy storage, fuel cells and various electronic devices. Among the types of materials available for these applications, nanostructured cationic block copolyelectrolytes offer mechanical integrity and well-defined conducting paths for ionic transport. To date, most cation...

Polyelectrolytes are polymers carrying either positively or negatively charged ionizable groups. The properties of these polymers in solutions and at charged surfaces depend on the fraction of dissociated ionic groups, solvent quality for polymer backbone, solution dielectric constant, salt concentration, and polymer–substrate interactions. In this review, we summarize the current development o...

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We study the effect of electrostatic interactions on the distribution function of the end-to-end distance of a single polyelectrolyte chain in the rod-like limit. The extent to which the radial distribution function of a polyelectrolyte is reproduced by that of a wormlike chain with an adjusted effective persistence length is investigated. Strong evidence is found for a universal scaling formul...

Nano films consisting of an alternating sequence of positively and negatively charged polyelectrolytes have been prepared by means of the electrostatic layer-by-layer (LBL) sequential assembly technique on treated and untreated mild steel wires. Inhibitor was encapsulated between cationic and anionic polyelectrolyte nano films. This paper mainly focuses on the effect of these nano-films of poly...

Weak polyelectrolytes have found extensive practical applications owing to their rich pH-responsive properties. In contrast, strong polyelectrolytes have long been regarded as pH-insensitive based on the well-established fact that the average degree of charging of strong polyelectrolyte chains is independent of pH. The possible applications of strong polyelectrolytes in smart materials have, th...

Insulin-loaded nanoparticles were prepared by ionotropic pre-gelation of alginate with calcium chloride followed by complexation between alginate and chitosan. The influence of the pH and stoichiometry relationship between polyelectrolytes providing individual particles with a nano-scale size was assessed by photon correlation spectroscopy (PCS) and scanning electron microscopy (SEM). Insulin– ...

Polyelectrolytes have been at the center of interdisciplinary research for many decades. In field polymer science and soft matter, they provided dimensions electrostatic interactions, which opens a vast variety opportunities new physical properties applications. biological polyelectrolytes are present in forms, from extracellular polysaccharides to complex DNA molecules proteins. This review di...