The effect of solvent quality on dilute and semidilute regimes of polymers in solution is studied by means of Monte Carlo simulations. The equation of state, adsorption near a hard wall, wall-polymer surface tension, and effective depletion potential are all calculated as a function of concentration and solvent quality. We find important differences between polymers in good and theta solvents. ...

A multi-scale framework is proposed for more realistic molecular dynamics simulations in continuum solvent models by coupling a molecular mechanics treatment of solute with a fluid mechanics treatment of solvent. This article reports our initial efforts to formulate the physical concepts necessary for coupling the two mechanics and develop a 3D numerical algorithm to simulate the solvent fluid ...

In considering the explanation of the recognized influence of the solvent upon the carcinogenic effectiveness of a dissolved carcinogen we have focussed our attention upon the physical factors which affect the availability of the carcinogen to the tissues in situ. An attempted formulation (see Discussion) of a possible mechanism of transfer from the solvent to the nearby affected tissue suggest...

an oral suspension could a suitable dosage form for the geriatric patients. the calcium alginate coated ion exchange resinate of propranolol hydrochloride were prepared using amberlite ir-120 by solvent evaporation. microcapsules of propranolol hydrochloride resinate were prepared by solvent evaporation technique,the suspensions were prepared by using deionised water as the vehicle. methyl cell...

Submitted for the MAR14 Meeting of The American Physical Society An in situ GISAXS study of BCP thin films during annealing in selective solvent vapor: Solvent removal effects in films of different initial thickness1 ILJA GUNKEL, Lawrence Berkeley Natl Lab, XIAODAN GU, University of Massachusetts Amherst , ALEXANDER HEXEMER, Lawrence Berkeley Natl Lab, THOMAS RUSSELL, University of Massachusett...

In striking contrast to simple polymer physics theory, which does not account for solvent effects, we find that physical confinement of solvated biopolymers decreases solvent entropy, which in turn leads to a reduction in the organized structural content of the polymer. Since our theory is based on a fundamental property of water-protein statistical mechanics, we expect it to have broad implica...

The inkjet printing machine was initially used on ceramic parts as a small device in designing and advertising offices limitedly. In recent years, this device has been applied professionally to create high-quality patterns in the industry. In this method, liquid ceramic ink is sprayed on the specified parts by piezoelectric nozzles and after drying and discharging, the organic matter is baked a...

We report that alkanethiol-capped Au nanoparticles can be linearly placed by toluene with its physical properties as well as its wettability in the presence of the nanoparticles. It is visually confirmed that toluene can be pinned with the aid of the nanoparticles to transport the nanoparticles to pinned contacts and to form linear placements. Whether the nanoparticles in various solvents can b...

A new CO2/CH4 gas separation process is presented in this paper. Capture of CO2 from natural gas is carried out using an n-alkane solvent in a conventional physical absorption process. A methodology to find optimal process condition and solvent has been developed using an advanced equation of state (SAFT-VR), process modelling-optimisation software (gPROMS), and detailed process cost estimation...