نتایج جستجو برای: photocatalytic reduction

تعداد نتایج: 505956  

Journal: :Chemical communications 2015
Bernd Mühldorf Robert Wolf

The enhanced reduction potential of riboflavin tetraacetate coordinating to scandium triflate enables the challenging photocatalytic C-H oxidation of electron-deficient alkylbenzenes and benzyl alcohols.

ژورنال: سلامت و محیط زیست 2018

Background and Objective: Chromium is present in two oxidation forms of Cr(III) and Cr(VI). Cr(III) is less toxic than Cr(VI). The aim of this article was to optimize an artificial neural network structure in modeling the photocatalytic reduction of Cr(VI) by TiO2-P25 nanoparticles. Materials and Methods: In this work, an artificial neural network (ANN) for the modeling photocatalytic reductio...

2014
Tao Xian Hua Yang Lijing Di Jinyuan Ma Haimin Zhang Jianfeng Dai

UNLABELLED SrTiO3-graphene nanocomposites were prepared via photocatalytic reduction of graphene oxide by UV light-irradiated SrTiO3 nanoparticles. Fourier transformed infrared spectroscopy analysis indicates that graphene oxide is reduced into graphene. Transmission electron microscope observation shows that SrTiO3 nanoparticles are well assembled onto graphene sheets. The photocatalytic activ...

Journal: :ChemPhotoChem 2021

The increasing number of devastating environmental disasters in recent years is ascribed to a changing climate due the steady increase concentration carbon dioxide atmosphere. With this mind, search for ways recycle and transform CO2 into more useful products has received significant attention become an issue global concern. activation is, however, very energy intensive endeavor use renewable s...

2014
Ştefan Neaţu Juan Antonio Maciá-Agulló Hermenegildo Garcia

The reduction of carbon dioxide to useful chemicals has received a great deal of attention as an alternative to the depletion of fossil resources without altering the atmospheric CO2 balance. As the chemical reduction of CO2 is energetically uphill due to its remarkable thermodynamic stability, this process requires a significant transfer of energy. Achievements in the fields of photocatalysis ...

2017
Philipp Kurz Bernhard Spingler

Two series of complexes MX(diimine)(CO)(3)] (M = Tc, Re) have been prepared, fully characterised and investigated for their ability to act as photocatalysts for the reduction of CO2 to CO. One series consists of complexes with different aromatic diimine ligands while keeping X = Brconstant. The second series describes complexes with diimine = 2,2-bipyridine and variations in the anionic ligand ...

2016
Guanjie Xing Lanxiao Zhao Tao Sun Yiguo Su Xiaojing Wang

In this work, we report on the synthesis of nitrogen doped SrTiO3 nanoparticles with efficient visible light driven photocatalytic activity toward Cr(VI) by the solvothermal method. The samples are carefully characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, UV-Vis diffuse reflectance spectroscopy and photocatalytic test. It is found that nitroge...

Co-doped ZnO nanoparticles with different Cobalt contents were prepared by direct precipitation method. The materials were characterized by XRD, SEM and TEM techniques. The XRD results indicated that the particle size of pure ZnO and Co-doped ZnO is about 30-45nm. The toxic Cr(VI) in industrial wastewaters can be removed by a reduction from Cr(VI) to Cr(III). The reduction of Cr(VI) to Cr(III) ...

2017
Lisa A. Tedesco James T. Laney Li Yu

Semiconductor Nanomaterials in Photocatalytic Bipyridine Reduction and H2 Generation By Li Yu Semiconductor nanoparticles have been used in the study of proton coupled electron transfer from CdS quantum dots (QDs) to N-heptyl-4,4’-bipyridinium (bPYD) and photocatalytic H2 generation with Pt tipped CdS nanorods (NRs) under alkaline solutions. For the QDs/bPYD system, transient absorption (TA) sp...

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