A phase diagram of argon based upon percolation transition loci determined from literature experimental p-V isotherms, and simulation values using a Lennard-Jones model shows three fluid phases. The liquid phase spans all temperatures, from a metastable amorphous ground state at 0 K, to ultra-high T. There is a supercritical mesophase bounded by percolation transition loci, and a gas phase. Int...

We compute the equilibrium phase diagram of two simple models for patchy particles with three and five patches in a very broad range of pressure and temperature. The phase diagram presents low-density crystal structures which compete with the fluid phase. The phase diagram of the five-patch model shows re-entrant melting, in analogy with the previously studied four-patch case, a metastable gas-...

We numerically calculate the equilibrium phase diagram of one-patch particles with 30% patch coverage. It has been previously shown that in the fluid phase these particles organize into extremely long tubelike aggregates (G. Munaò et al. Soft Matter 2013, 9, 2652). Here, we demonstrate by means of free-energy calculations that such a disordered tube phase, despite forming spontaneously from the...

BZ26-6 Oilfield is a kind of deep metamorphic rock buried-hill volatile oilfield in Bohai Sea, China. Its early development plan restricted due to the simultaneous production oil and gas large sections reservoirs, unclear understanding formation fluid properties uncertainty gas-oil interface. Through theoretical research on phase recovery experimental analysis crude characteristics original for...

Motivated by the recent realization of a Cr Bose-Einstein condensate, we consider the phase diagram of a general spin-three condensate as a function of its scattering lengths. We classify each phase according to its reciprocal spinor, using a method developed in a previous work. We show that such a classification can be naturally extended to describe the vortices for a spinor condensate by usin...

pyrolysis of low density polyethylene (ldpe) by equilibrium fluid catalytic cracking (fcc) was studied in a stirred reactor under different process parameters. in this work, the effect of process parameters such as degradation temperature (420-510°c), catalyst/polymer ratio (0-60%), carrier gas type (h2, n2, ethylene, propylene, ar and he), residence time and agitator speed (0-300 rpm) on the c...

We calculate the full phase diagram of spherical charged colloidal particles using Monte Carlo free energy calculations. The system is described using the primitive model, consisting of explicit hard-sphere colloids and point counterions in a uniform dielectric continuum. We show that the gas-liquid critical point becomes metastable with respect to a gas-solid phase separation at colloid charge...

– We study theoretically the dimensional crossover from a three-dimensional elongated condensate to a one-dimensional condensate as the transverse degrees of freedom get frozen by tight confinement, in the limit of small density fluctuations, i.e. for a strongly degenerate gas. We compute analytically the radially integrated density profile at low temperatures using a local density approximatio...