Lanthanide perovskite oxides are mentioned as material for hydrogen peroxide sensor because they can catalytically decompose hydrogen peroxide in an aqueous medium. The catalytic properties of these perovskite oxides to hydrogen peroxide are suggested due to their oxygen vacancies influenced by the oxide non-stoichiometry. In this paper, we investigate the catalytic hydrogen peroxide decomposit...

Point defects can affect considerably the structural, magnetic, and transport properties of perovskite-structure materials with chemical formula ABO3. Oxygen vacancies (VO), for example, enable ionic conductivity in perovskite-based solid solutions to be used for electrochemical applications such as solid oxide fuel and electrolysis cells [1]. Likewise, VO can distort significantly the equilibr...

The perovskite structure is one of the most versatile structures for tailoring the properties of materials. The range of properties of perovskites varies from superconductivity to ferroelectricity, magnetoresistance to magnetocapacitance, and laser host properties to name a few. In particular, the perovskite oxides have been explored for their dielectric and magnetic properties. Traditionally, ...

Sveinbjörnsson, K. 2018. Preparation and Characterization of Lead Halide Perovskites. Towards sustainable, cost-effective and upscalable solar cell manufacture. Digital Comprehensive Summaries of Uppsala Dissertations from the Faculty of Science and Technology 1628. 84 pp. Uppsala: Acta Universitatis Upsaliensis. ISBN 978-91-513-0229-4. The perovskite solar cell (PSC) is a recent contender with...

An oxide semiconductor (perovskite-type Mn2 O3 ) is reported which has a narrow and direct bandgap of 0.45 eV and a high Vickers hardness of 15 GPa. All the known materials with similar electronic band structures (e.g., InSb, PbTe, PbSe, PbS, and InAs) play crucial roles in the semiconductor industry. The perovskite-type Mn2 O3 described is much stronger than the above semiconductors and may fi...

Co-doping of yttrium doped mixed barium cerate/zirconate perovskite (BCZY) with small amounts of Pr (BCZYP) substantially increases electrical conductivity while retaining structural and chemical stability. BCZYP is predominantly a proton conductor at temperatures up to 600-650 ̊C, whereas it is a mixed proton/oxide ion/electron conductor at higher temperatures. The co-doped BCZYP perovskite can...

Organic-inorganic perovskites have shown promise as high-performance absorbers in solar cells, first as a coating on a mesoporous metal oxide scaffold and more recently as a solid layer in planar heterojunction architectures. Here, we report transient absorption and photoluminescence-quenching measurements to determine the electron-hole diffusion lengths, diffusion constants, and lifetimes in m...

Using an extension of a first-principles method developed by King-Smith and Vanderbilt Phys. Rev. B, 49, 5828 1994 , we investigate the effects of in-plane epitaxial strain on the ground-state structure and polarization of eight perovskite oxides: BaTiO3, SrTiO3, CaTiO3, KNbO3, NaNbO3, PbTiO3, PbZrO3, and BaZrO3. In addition, we investigate the effects of a nonzero normal stress. The results ar...

A ZnO compact layer formed by electrodeposition and ZnO nanorods grown by chemical bath deposition (CBD) allow the processing of low-temperature, solution based and flexible solid state perovskite CH3NH3PbI3 solar cells. Conversion efficiencies of 8.90% were achieved on rigid substrates while the flexible ones yielded 2.62%.

Monocrystalline mesoporous BiFeO3 crystals were obtained via a multi-step single-crystal to single-crystal transformation of a coordination polymer, Bi[Fe(CN)6]·4H2O. This unique transformation process significantly decreased the crystallization temperature of perovskite oxide without losing high crystallinity.