The applicability of a recently proposed force field of Calero et al. (J. Am. Chem. Soc., 2004, 126, 11377) to Na-MOR zeolites is evaluated. The Henry law coefficients of ethane and C(5)-C(9) as well as the adsorption isotherms of ethane, propane, butane, and hexane in various Na-MOR zeolites are computed and compared with experimental values. These comparisons show that the new force field is ...

This study deals with influence of 1vol% and 2 vol% zeolites to survival of Salmonella typhimurium, S. seftenberg and indicator bacteria (psychrophilic, mesophilic, coliform and faecal coliform) in the solid fraction of pig slurry from agricultural wastewater treatment plant. PVC bottles with openings served as test carriers. In solid fraction with 1 vol% zeolites S. typhimurium survived for 9 ...

Nanoporous acid catalysts such as zeolites form the backbone of catalytic technologies for refining petroleum. With the promise of a biomass economy, new catalyst systems will have to be discovered, making shape-selective base catalysts especially important because of the high oxygen content in biomass-derived feedstocks. Strongly basic zeolites are attractive candidates, but such materials are...

Low silica zeolites are synthesized generally by sol-gel method in water. In this study, efforts were made to prepare low silica zeolites from sodium aluminate and sodium silicate, in the presence of alcohols, at 373 K under an atmospheric pressure. It was of our special interest to investigate how the addition of various alcohols into water affects the type of zeolites synthesized during cryst...

Zeolites are crystalline hydrated tektoalumosilicates consisting of a three-dimensional framework of SiO4 4and AlO4 5tetrahedra linked through shared oxygen atoms. The heulandite group of zeolites including clinoptilolite are the most abundant zeolites in nature 1, 2 . Clinoptilolite is used in a wide range of industrial and agricultural applications, particularly in animal nutrition. Dietary i...

Zeolites containing Zn in their frameworks are promising materials for ion-exchange and catalysis because of their unique ion-exchange capabilities and characteristic Lewis acidity. However, expensive organic compounds often required in their synthesis can prevent their practical uses. Here, a facile organic-free synthesis route for new zincoaluminosilicate zeolites having MOR topology, in whic...

The database of prospective zeolites (www. hypotheticalzeolites.net) has been screened in search of feasible zeolites. Previous criteria of zeolite feasibility have been reviewed, based on descriptors such as energy, density, average and distribution of ring sizes, and more importantly that of Li et al. (LID criteria) presented recently [Angew. Chem. Int. Ed. 2013, 52, 1673], based on Si–O, O.....

Surfactant-templating is one of the most versatile and useful techniques to implement mesoporous systems into solid materials. Various strategies based on various interactions between surfactants and solid precursors have been explored to produce new structures. Zeolites are invaluable as size- and shape-selective solid acid catalysts. Nevertheless, their micropores impose limitations on the ma...

Crystals of zeolites with intricate micropores have been widely used in industry as heterogeneous catalysts, in particular as solid acid catalysts in the fields of oil refining and petrochemistry. However, relatively small individual micropores in zeolites such as Beta, ZSM-5, and Y strongly influence mass transport to and from the active sites located within them, severely limiting the perform...

Introduction and background: Zeolite minerals are hydrated framework aluminosilicates common to altered volcanic and volcanoclastic rocks, and the soils derived from them [1]. The mineralogy, chemistry, textural context, and abundance of zeolites provides insight into chemical weathering, hydrothermal, and metamorphic processes on Earth, in a variety of climates and tectonic settings. Zeolites ...