Two polyanions [SeI V2 PdII4 WVI14 O56 H]11- and [SeI V4 PdII4 WVI28 O108 H12 ]12- are the first hybrid polyoxometalates in which classical (Group 5/6 metal based) and non-classical (late transition-metal based) polyoxometalate units are joined. Requiring no supporting groups, this co-condensation of polyoxotungstate and isopolyoxopalladate constituents also provides a logical link between POM-...

The use of weak bases and mild conditions is currently the most sustainable attractive synthetic approach for preparation late-transition metal complexes, some which are widely used in catalysis, medicinal chemistry materials science. Herein, cuprate, aurate or palladate species a continuous flow CuI, AuI PdII-NHC complexes reported. All reactions examined proceed under extremely make technical...

The title compound, hexa-kis-[μ3-1,2-bis-(tri-fluoro-meth-yl)ethene-1,2-di-thiol-ato]-octa-hedro-hexa-palladium(II), [Pd(C4F6S2)]6, crystallizes as its benzene solvate, [Pd(tfd)]6·2.5C6H6, where tfd is the di-thiol-ene S2C2(CF3)2. The mol-ecular structure of [Pd(tfd)]6 is of the hexa-metallic cube type seen previously in three examples of hexa-meric homoleptic palladium monodi-thiol-ene structu...

Catalytic transformations involving Pd s-alkyl or s-aryl intermediates are widely used in organic synthesis and offer attractive routes to many valuable products. However, the vast majority of these reactions proceed by Pd/Pd mechanisms. As a result, the diversity of structures/bonds that can be constructed is constrained by the limitations of this redox cycle. Recent studies have explored the ...