DFT-GGA method of Perdew-Burke-Ernzerhof (PBE) is used with aug-cc-PVTZ, 6-311++G**, and Def2-TZVP large basis sets to study the hydrogen bond interactions between oxygen lone pair as a donor electron with hydrogen atom connected to the aniline’s nitrogen as an electron acceptor (H2O···HNH-Ph), and nitrogen lone pair with hydrogen of water molecule (Ph-H2N···HOH...

an injective map f : e(g) → {±1, ±2, · · · , ±q} is said to be an edge pair sum labeling of a graph g(p, q) if the induced vertex function f*: v (g) → z − {0} defined by f*(v) = (sigma e∈ev) f (e) is one-one, where ev denotes the set of edges in g that are incident with a vetex v and f*(v (g)) is either of the form {±k1, ±k2, · · · , ±kp/2} or {±k1, ±k2, · · · , ±k(p−1)/2} u {k(p+1)/2} accordin...

An extractive spectrophotometric method is described for the assay of sitagliptin phosphate in bulk drug and in tablets. Sitagliptin phosphatewas extracted as an ion-pair complex from the solution containing Eriochrome black T and 0.1N HCl into chloroform and the absorbance of the complex was measured at 500nm.The working conditions of the method were investigated and optimized. Beer’s law plot...

A matrix $Pintextmd{C}^{ntimes n}$ is called a generalized reflection matrix if $P^{H}=P$ and $P^{2}=I$‎. ‎An $ntimes n$‎ ‎complex matrix $A$ is said to be a reflexive (anti-reflexive) matrix with respect to the generalized reflection matrix $P$ if $A=PAP$ ($A=-PAP$)‎. ‎In this paper‎, ‎we introduce two iterative methods for solving the pair of matrix equations $AXB=C$ and $DXE=F$ over reflexiv...

a simple, precise, rapid and low-cost potentiometric method for diclofenac determination in pharmaceuticals is proposed. a new diclofenac-sensitive electrode was constructed by incorporating the diclofenac ion pair complex with butyl rhodamine b into graphite matrix. the electrode exhibited a linear response over the concentration range of 1 × 10-4 – 5 × 10-2 mol l-1, a detection limit of 3.9×1...

Background: Spontaneous abortion (SAb) is the most common complication of early pregnancy. Numerous risk factors are associated with an increased risk of pregnancy loss such as: Maternally age, previous spontaneous abortion, prolonged ovulation to implantation, Gravidity, Interval Prolonged time to pregnancy, Balanced chromosomal translocations and Genetic disorders. The aim of this study was t...