The investigation of the lattice-parameter ratios of tetrahedral and hexagonal-rhombohedral inorganic compounds, as reported by Constant & Shlichta [(2003), Acta Cryst. A59, 281-282], has been extended to the structural data found for organic and metal-organic compounds (CSD), for bio-macromolecular crystals (PDB) and for inorganic materials (ICSD). In this first part of the series, the frequen...

Crystalline organic compounds have been observed to react in a number of cases in a manner which suggests that the process is dependent on the geometry of the disposition of reactive groups in the crystal lattice. Such a process, first observed with inorganic reactions, has been designated by Kohlschuetter' as "topochemical," and several criteria may be used to show that a reaction falls into t...

A direction sensitive dark matter detector using organic crystals is being developed. It exploits the anisotropic scintillation efficiency of organic crystals with respect to the direction of nuclear recoils relative to crystallographic axes. A variation of about 7% was observed in the scintillation efficiency of carbon recoils in a stilbene crystal for recoil energies of 30 keV to 1MeV. We hav...

This paper describes the rapid fabrication of an organic/inorganic multi-layered composite film: Parylene-poly(vinyl alcohol) (PVA)-calcium carbonate (CaCO3) composite film. CaCO3 crystals on PVA film were sandwiched between Parylene films, and thermal bonding was carried out after folding the sandwiched crystals eight times. Using this method, a millimeterthick 48-layered organic/inorganic com...

Organic salts composed of chiral amines and sulfonic acid with high hyperpolarizability allowed the construction of polar crystals with incorporated guest molecules. The polarity of the crystals was precisely regulated by employing suitable guest molecules. As a result, the crystals generated a strong second harmonic generation property.

A template-directed method for the synthesis and organization of partially oxidized polypyrrole (PPy) nanoscale arrays within the solvent channels of glutaraldehyde-cross-linked lysozyme single crystals is presented. Macroscopic single crystals of the periodically arranged protein-polymer superstructure are electrically conductive, insoluble in water and organic solvents, and display increased ...

We have previously identified proteins extracted from calcium oxalate (CaOx) and calcium phosphate (CaP) crystals generated experimentally in vitro in whole urine of healthy controls and stone formers. No significant differences were detected between protein components in matrices of crystals obtained from both groups. The aim of the present study was to estimate the amounts of six proteins ide...

Urine contains variable amounts of organic matter derived from cell degradation. The cellular detritus is composed by membranous and cytosolic glycoproteins, etc. The aim of this paper was to study the role of organic matter in calcium oxalate crystal development and to evaluate the action of some crystallization inhibitors on this process. Crystallization studies were carried out on urine in s...