Only one (trans(O5)-Na[Rh(ED3AP)]?3H2O) of possible two isomers was synthesized and characterized by single crystal X-ray analysis, IR UV?Vis spectroscopy. Computational analysis both performed with three levels theory (B3LYP/TZV, BP86/TZV, OPBE/TZV), which gave consistent results. The more stable isomer total energy ligand field stabilization (LFSE) trans(O5) appeared in synthesis. calculation...

The compound LLPNP crystallizes in orthorhombic system, P21 21 21 space group with four molecules in the asymmetric unit. The crystal data for LLPNP is tabled. The lysine molecule (C1-C6/N1/N2/O1/O2) is protonated while the paranitrophenol molecule is deprotonated (C7-C12/N3/O3/O4/O5). The paranitrophenol moiety makes a dihedral angle of 85.87 (9)° with the lysine moiety which shows that they a...

In this short article the accurate labeling of the O4,5 edges of the light actinides is addressed. The O4 and O5 edges are both contained in what is termed the 'giant resonance' and the smaller 'pre-peak' that is observed is a consequence of first-order perturbation by the 5d spin-orbit interaction. Thus, the small prepeak in the actinide 5d → 5f transition should not be labeled the O5 peak, bu...

The ability of some strains of Vibrio parahaemolyticus to hydrolyze urea (uh+) can be used as a marker to predict which strains isolated from molluscan shellfish harvested in the Pacific Northwest are potentially pathogenic. The thermostable direct hemolysin-producing (TDH+) characteristic is a marker that is correlated with potential pathogenicity, and all of the TDH+ strains that we have isol...

Social stigma is a major challenge among the patients with mental illness, their families and the health care providers. Not only the patient with psychological disorders, but also who has an infectious disease suffer social stigma. Stigma refers to an extreme and unusual disapproval of a person from the other members of society. Stigma is a Greek word that in its origins referred to a type of ...

We discuss geometry underlying orientifolds with non-trivial NS-NS B-flux. If D-branes wrap a torus with B-flux the rank of the gauge group is reduced due to non-commuting Wilson lines whose presence is implied by the B-flux. In the case of D-branes transverse to a torus with B-flux the rank reduction is due to a smaller number of D-branes required by tadpole cancellation conditions in the pres...