UNLABELLED Nitric oxide (NO) plays an important signaling role in all domains of life. Many bacteria contain a heme-nitric oxide/oxygen binding (H-NOX) protein that selectively binds NO. These H-NOX proteins often act as sensors that regulate histidine kinase (HK) activity, forming part of a bacterial two-component signaling system that also involves one or more response regulators. In several ...

The oxygen isotope composition of nitrogen oxides (NOx) in the atmosphere is a useful tool for understanding the oxidation of NOx into nitric acid / nitrate in the atmosphere. A set of experiments was conducted to examine change in isotopic composition of NOx due to NOx–O2– O3 photochemical cycling. At low NOx / O2 mixing ratios, NOx became progressively and nearly equally enriched in 17O and 1...

main purpose of current study is development of a new multi zone model for direct injection diesel engines. zone configuration is based on conical shape of spray. siebers’s correlation is used for spray cone angle calculation. experimental data are used for calculation of fuel inlet mass flow rate. fuel diffusion in different zones is calculated using fick’s law. a chemical kinetics mechanism c...

T he self-cleansing capacity of the atmosphere is largely dependent on the concentration level of hydroxyl radicals (OH) (1). Nitrous acid (HONO) is an important precursor of OH in the troposphere (2–4). Based on observations of HONO and its budget in the Po Valley region in Italy, we concluded that HONO formation in a sunlit layer separated from the ground surface is from a gas-phase source co...

The major pollutants from diesel engines are NOx and soot. NOx and soot emissions are of concerns to the international community. They have been judged to pose a lung cancer hazard for humans as well as elevating the risk of non-cancer respiratory ailments. These emissions react in the atmosphere in the presence of sunlight to form ground-level ozone. Ground-level ozone is a major component of ...

Aldehydes are an important class of products from atmospheric oxidation of hydrocarbons. Isoprene (2methyl-1,3-butadiene), the most abundantly emitted atmospheric non-methane hydrocarbon, produces a significant amount of secondary organic aerosol (SOA) via methacrolein (a C4-unsaturated aldehyde) under urban high-NOx conditions. Previously, we have identified peroxy methacryloyl nitrate (MPAN) ...

The fate of char-N (nitrogen removed from the coal matrix during char oxidation) has been widely studied at fluidized bed conditions. This work extends the study of char-N to pulverized coal conditions. Coal chars from five parent coals were prepared and burned in a laboratory-scale pulverized coal combustor in experiments designed to identify the parameters controlling the fate of char-N. The ...

pH is highly variable in different tissues and affects many enzymatic reactions in neutrophils. In response to calcium ionophores such as A23187 and ionomycin, neutrophils undergo nicotinamide adenine dinucleotide phosphate oxidase (NOX)-independent neutrophil extracellular trap (NET) formation (NETosis). However, how pH influences calcium-dependent Nox-independent NET formation is not well und...