The effects of varying the silica source on synthesis of NaX zeolite crystals via conventional hydrothermal method have been investigated. Five different silica sources were selected while other parameters like Al source, reaction and aging time, SiO2/Al2O3 molar ratio and temperature were same. The prepared products were characterized by XRD technique. The results showed that different cry...

The title compound, [FeCl2(C12H26N4)]PF6, is the first mononuclear Fe3+ complex of an ethylene cross-bridged tetraaza-macrocycle to be structurally characterized. Comparison with the mononuclear Fe2+ complex of the same ligand shows that the smaller Fe3+ ion is more fully encapsulated by the cavity of the bicyclic ligand. Comparison with the mu-oxo dinuclear complex of an unsubstituted ligand o...

a series of experiments were designed to utilize the taguchi method for investigating the effects of important parameters on the synthesis of nax zeolite and to find the best conditions of synthesis. an l9 orthogonal design of taguchi approach was applied to design experiments consisting of 9 trails. the effect of molar composition, including sio2/al2o3 and na2o/al2o3 ratios, and the crystalliz...

The design of a semiconductor or composite system—with applications in materials science—is complex because its morphology and structure depend on several parameters. These parameters are the precursor type, solvent, pH solution, synthesis approach, shaping agents. This study gives meaningful insight regarding such WO3 materials. By systematically alternating (sodium tungstate dihydrate—NWH, am...

in this investigation we synthesized nax-nanozeolite by hydrothermal crystallization conditions.these nanoparticles were prepared at different conditions in a temperature controlled shaker. thesynthesized zeolites were characterized by instrumental analysis methods, such as x-raydiffraction (xrd), x-ray fluorescence (xrf), scanning electron microscopy (sem) andtransmission electron microscopy (...

In this investigation we synthesized NaX-Nanozeolite by hydrothermal crystallization conditions.These nanoparticles were prepared at different conditions in a temperature controlled shaker. Thesynthesized zeolites were characterized by instrumental analysis methods, such as X-raydiffraction (XRD), X-ray fluorescence (XRF), scanning electron microscopy (SEM) andtransmission electron microscopy (...

We give a natural obstruction theoretic interpretation to the first Pontryagin class in terms of Courant algebroids. As an application we calculate the class of the stack of algebras of chiral differential operators. In particular, we establish the existence and uniqueness of the chiral de Rham complex. Sverhu molot, snizu serp, Зto – nax, Sovetski gerb. Hoqexь жni, a hoqexь ku ...

silicon and aluminum sources are most important reactants in the synthesis of zeolite. the use of the silicon source has an important effect on the crystallization of zeolites. also, it can change the properties of the end product. this work reports the influence of three common commercial silica sources such as colloidal silica (ludox am-30), fumed silica and water glass on the crystallinity o...

We review recent applications of jump models for diffusion in zeolites. We describe the results of a coarse-grained model of the interplay between zeolite anisotropy and disorder, finding that certain disorder patterns can change how anisotropy controls membrane permeation. We show the results of a lattice model for single-file diffusion in zeolite membranes, demonstrating how single-file motio...

We report some interesting results of the chemical reactivity of thiolate-protected [Au(25)(SCH(2)CH(2)Ph)(18)](0) nanoclusters with two types of salts, including tetraoctylammonium halide (TOAX) and NaX. At the early stage of the reaction, [Au(25)(SCH(2)CH(2)Ph)(18)](0) was found to spontaneously convert to its anionic form ([Au(25)(SCH(2)CH(2)Ph)(18)](-)) in the presence of either type of sal...