The temperature dependence of core loss in cobalt substituted Ni-Zn-Cu ferrites was investigated. Co ions are known to lead to a compensation of the magnetocrystalline anisotropy in Ni-Zn ferrites, at a temperature depending on the cobalt content and the Ni / Zn ratio. We observed similar behaviour in Ni-Zn-Cu and it was found that the core loss goes through a minimum around this magneto-crysta...

It is shown that an electrodeposited Zn-Ni-Cd alloy coating produced from sulfate electrolyte inhibits the discharge of hydrogen on carbon steel. The newly developed ternary alloys have approximately ten times higher corrosion resistance when compared to a Zn-Ni alloy. Hydrogen permeation characteristics of Zn-Ni-Cd alloy coatings were studied and compared with those of a bare and a Zn-Ni alloy...

Twenty-six metals and the oxidative status in 71 patients affected by Parkinson's disease and 44 healthy individuals were compared in order to identify potential biomarkers of the disease. In the patients, the following significant imbalances were found (p < or = 0.05): i) in serum, an increment of Ca, Mg, Ni, Si and V, and a decrement of Cd, Co, Fe, Li, Sn, Zn and Zr; ii) in blood, raised leve...

the concentration of cu, mn, ni and zn were determined in tomatoes and onions samples using atomic absorption spectrometry. a total of 32 samples each of tomatoes and onions were collected from the exposed and control sites for analysis. the trace metals (cu, mn, ni and zn) concentration in tomatoes wee found to be 6.2406, 6.5521 , 5.7375 and 8.9297 mg/kg-1, respectively. while those of onions ...

InrS is a Ni(II)-responsive, CsoR/RcnR-like, DNA-binding transcriptional repressor of the nrsD gene, but the Ni(II) co-ordination sphere of InrS is unlike Ni(II)-RcnR. We show that copper and Zn(II) also bind tightly to InrS and in vitro these ions also impair InrS binding to the nrsD operator-promoter. InrS does not respond to Zn(II) (or copper) in vivo after 48 h, when Zn(II) sensor ZiaR resp...

Concentrations of heavy metals (As, Co, Cu, Ni, Mo, Pb and Zn) are studied in the soil of Shiraz industrial complex zone, south Shiraz, Iran to asses metal contamination due to industrialization, urbanization and agricultural activity. Soil samples were collected from three different depths. The A and C depths are enriched with metals such as Ni, As, Mo, Cu, Pb and Zn, compared with the B depth...

concentrations of six heavy metals including cr, mn, ni, pb, v and zn were determined in topsoil (from 47 grid cells), surface water (4 streams) and groundwater (8 wells and 4 qanats) from an agriculturalarea located at south part of the iranian capital, near the tehran oil refinery. concentrations of the elementswere measured using flame and flameless atomic absorption spectrometry. based on t...

Oxidations of a trigonal-bipyramidal, high-spin Ni(II) dithiolate complex of a pentadentate, N3S2-donor ligand, N1,N9-bis(imino-2-mercaptopropane)-1,5,9-triazanonane) nickel(II), and the structurally analogous Zn(II) complex, lead to oxidations of the ligand. Oxidation of the Ni(II) complex with I2 produces a novel Ni(II) macrocyclic cationic complex containing a monodentate disulfide ligand (2...

Glyoxalase pathway plays an important role in stress adaptation and many clinical disorders. The first enzyme of this pathway, glyoxalase I (GlxI), uses methylglyoxal as a substrate and requires either Ni(II)/Co(II) or Zn(II) for activity. Here we have investigated the origin of different metal ion specificities of GlxI and subsequent pattern of inheritance during evolution. Our results suggest...