Arsenic (As) contaminated aquifers contain iron minerals and clays that strongly bind As at their surfaces. It was suggested that As mobilization is driven by natural organic matter (including fulvic acids (FA) and humic acids (HA)) present in the aquifers either via providing reducing equivalents for reductive dissolution of Fe(III) (hydr)oxides or via competitive desorption of As from the min...

Nitroaromatic compounds are produced and used in large quantities worldwide and are frequently detected contaminants in the environment. Sorption is one of the fundamental processes controlling the transport and availability of nitroaromatics, but previous studies have focused mainly on sorption to model clay minerals, whereas little attention has been paid to the sorptive interactions with nat...

UNLABELLED The ESKAPE (Enterococcus faecium, Staphylococcus aureus, Klebsiella pneumoniae, Acinetobacter baumannii, Pseudomonas aeruginosa, and Enterobacter species) pathogens cause an increasing number of nosocomial infections worldwide since they escape the inhibitory effect of the available antibiotics and the immune response. Here, we report the broad-spectrum and potent antibacterial activ...

The grafting reaction between a trifunctional silylating agent and two kinds of 2:1 type layered silicates was studied using FTIR, XRD, TGA, and 29Si CP/MAS NMR. XRD patterns clearly indicate the introduction of 3-aminopropyltriethoxysilane (gamma-APS) into the clay interlayer. In the natural montmorillonite, gamma-APS adopts a parallel-bilayer arrangement, while it adopts a parallel-monolayer ...

ABSTR ACT: In a laboratory investigation, the effect of natural sunlight and UV light exposure on dissipation of fipronil insecticide from two soils (clay loam and sandy clay loam) and the effect of pH on the persistence of fipronil in aqueous medium were studied. Dissipation of fipronil insecticide under sunlight followed biphasic first order kinetics in both soils. The half-life of the insect...

Clayrock formations are under consideration to serve as host formation and geological barriers for radioactive waste repositories due to their favorable properties (low permeability, low diffusion coefficient, high retention capacity for radionuclides...). The currently on-going European CATCLAY project (EURATOM FP7) (www.catclay.org) is focused on understanding the fundamental processes govern...