In the title compound, C(18)H(19)N(5), the pyrimidine ring makes dihedral angles of 56.49 (9) and 70.88 (9)° with the phenyl rings. The dihedral angle between the two phenyl rings is 72.45 (9)°. No significant inter-molecular inter-actions are observed in the crystal structure.

The title compound, C(33)H(3)F(20)N(3)O(4), is a highly fluorinated organic imide that was isolated as an unexpected product from the reaction of 2,6-diamino-pyridine with 2,3,4,5,6-penta-fluoro-benzoyl chloride in a 1:2 molar ratio. The mol-ecule is located on a twofold axis and one of its symmetry-independent 2,3,4,5,6-penta-fluoro-benzoyl groups is disordered over two sets of sites, the occu...