RATIONALE Functionalization of carbon nanotubes (CNTs) generates complex systems that require the development of suitable characterization protocols. New techniques have been explored, and existing analytical and spectroscopic methods to characterize functionalized CNTs have been adapted. Presently, chemical characterization of functionalized CNTs (f-CNTs) remains a difficult task. METHODS Ma...

In this work, an efficient procedure for the functionalization of multiwalled carbon nanotube (MWCNTs) based on nitric acid oxidation was presented. The morphologies of MWCNTs oxidized under various conditions were characterized by scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR). The FTIR provided clear evidence for the presence of carboxylic groups (–COOH)...

The influence of multi-walled carbon nanotubes (MWCNT) on the structural dynamic behavior of MWCNT/epoxy nanocomposites was investigated. Two different types of MWCNTs, pristine MWCNT and functionalized MWCNT, were used in this study. Carboxylic acid-functionalized MWCNTs (MWCNT-COOH) were obtained by oxidation pristine MWCNTs via sonication in sulfuric-nitric acid and characterized by Fourier ...

Poly(trimethylene terephthalate) nanocomposites containing COOH functionalized multi-walled nanotubes were synthesized with in situ polymerization method. The microstructure of the nanocomposites was studied by SEM, in terms of the dispersion state of the nanotubes and the polymer–nanotube interface. The thermal behaviour, mechanical properties and conductivity of these resultant PTT/MWCNTs nan...

Multiwalled carbon nanotubes (MWCNTs) were covalently modified with different molecular weights 400 and 2000 poly(oxyalkylene)-amine bearing DGEBA epoxy (POA400-DGEBA and POA2000-DGEBA) oligomers via a grafting method. The weight-average molecular weights of POA400-DGEBA and POA2000-DGEBA were measured as 1623 and 9231 with polydispersity indices (PDIs) of 2.3 and 1.6, respectively. The oxidize...

BACKGROUND During production and processing of multi-walled carbon nanotubes (MWCNTs), they may be inhaled and may enter the pulmonary circulation. It is essential that interactions with involved body fluids like the pulmonary surfactant, the blood and others are investigated, particularly as these interactions could lead to coating of the tubes and may affect their chemical and physical charac...

The electrochemical sensor for detecting hydrogen sulfide was fabricated. H2S gas molecules pass through polytetrafluoroethylene membrane with 0.22 mm pore size. Carboxylated multi-walled carbon nanotubes (MWCNTs-COOH) were used to fabricate working and counter electrodes. It can be seen from Field Emission Scanning Electron Microscopy (FESEM) images of the working electrode that...

The creep and dynamic mechanical behavior of natural fiber/epoxy composites using functionalized multiwalled carbon nanotubes (MWCNTs) modified matrix were investigated. 0.4 wt% of MWCNTs functionalized with carboxylic acid groups (MWCNTs-COOH) were dispersed in epoxy and three-phase multiscale hybrid composites were processed by hot press. Natural fiber/epoxy two-phase composites without MWCNT...

This work presents an efficient method of supporting zirconia (ZrO2) on COOH functionalized multi-walled carbon nanotubes (ZrO2/MWCNTs(C)) via a microwave (MW)-assisted method, which can be used as catalyst for converting fructose to 5-HMF. The developed composite by the MW-assisted route shows highly dispersed ZrO2 with small sizes 4–5 nm support, could not achieved conventional hydrothermal s...

Pristine multiwall carbon nanotubes [MWCNTs] have been functionalized with various groups (-COOH, -SO3H, -PO3H2) using different single- and double-step chemical routes. Various chemical treatments were given to MWCNTs using hydrochloric, nitric, phosphoric, and sulphuric acids, followed by a microwave treatment. The effect of the various chemical treatments and the dispersion using a surfactan...