We present the chemical synthesis as well as charge transport measurements and calculations for a new tripodal platform based on a rigid 9,9'-spirobifluorene equipped with a phenylene-ethynylene wire. The transport experiments are performed with the help of the low-temperature mechanically controlled break junction technique with gold electrodes. By combining experimental and theoretical invest...

The stability and elasto-mechanical properties of tetragonal and cagelike or clathrate nanowires of Si are investigated and compared using molecular dynamics simulations. Our results show that cagelike nanowires, while possessing lesser density, are able to maintain their structural integrity over a larger range of strain conditions than the tetrahedral nanowires, making them a better candidate...

Oligoynes are archetypical molecular wires due to their 1-D chain of conjugated carbon atoms and ability to transmit charge over long distances by coherent tunneling. However, the stability of the oligoyne can be an issue. Here we address this problem by two stabilization methods, namely sterically shielding endgroups, and rotaxination to produce an insulated molecular wire. We demonstrate the ...

The influence of an electron-vibrational coupling on the laser control of electron transport through a molecular wire that is attached to several electronic leads is investigated. These molecular vibrational modes induce an effective electron-electron interaction. In the regime where the wire electrons couple weakly to both the external leads and the vibrational modes, we derive within a Hartre...

We present a technique to calculate the transport properties through onedimensional models of molecular wires. The calculations include inelastic electron scattering due to electron-lattice interaction. The coupling between the electron and the lattice is crucial to determine the transport properties in one-dimensional systems subject to Peierls transition since it drives the transition itself....

Molecular-scale electronics is mainly concerned by understanding charge transport through individual molecules. A key issue here is the charge transport capability through a single--typically linear--molecule, characterized by the current decay with increasing length. To improve the conductance of individual polymers, molecular design often either involves the use of rigid ribbon/ladder-type st...

A spin-boson model based on local pseudo-spins acting in the electronic occupation number space is suggested and used to describe the thermally activated interelectrode current through a molecular wire. Utilizing the density matrix technique a unified description is achieved of all those kinetic processes which contribute to the inelastic current formation. These processes cover a specific supe...

The effect of laser fields on electron transport through a molecular wire weakly coupled to two leads is investigated. The molecular wire acts as a coherent quantum ratchet if the molecule is composed of periodically arranged, asymmetric chemical groups. This setup presents a quantum rectifier with a finite dc response in the absence of a static bias. The nonlinear current is evaluated in close...