Size-controllable Pt nanoparticles ranging from 1.3 to 2.3 nm were successfully loaded onto ZSM-5 (Pt-x/ZSM-5, where x is the mean diameter of the Pt nanoparticles). Catalytic tests in complete oxidation of toluene as a model for VOC removal show that Pt-1.9/ZSM-5 has the highest activity, due to a balance of Pt dispersion and Pt(0) proportion.

Phenol is an important industrial intermediate for the production of various chemicals such as bisphenol A, phenolic resins, caprolactam, alkylphenols and adipic acid. The cumene hydroperoxide process is the currently used industrial method to produce phenol. Its environmentally stressing aspects have spurred research to replace this process with more benign approaches such as the direct oxidat...

Abstract Dehydroaromatization of methane (MDA) reaction was investigated over platinum modified Mo/H-ZSM-5 catalysts which were pre-carbided at 750 °C. The influence on the catalytic performance and product selectivity for MDA 700 °C studied. presence led to a slight decrease in conversion from 7.5 4.2%. Aromatic selectivities above 90% obtained with containing low loadings (0.5 1.0 wt.%), benz...

In the microwave and radio frequency (RF) plasma catalytic reaction at room temperature, the oxidative coupling of methane (OCM) over transitional metals loaded on ZSM-5 has been carried out. The transitional metals, Fe, Ni, Co and Cu (1B family element), loaded on ZSM-5 have been tested for the OCM using the plasma catalytic reaction. In this work, the conversion of methane to C2 products has ...

Zeolites have been successfully applied as catalysts in the pyrolysis of plastics to obtain valuable lower molecular weight hydrocarbon compounds. In present work, mordenite was directly synthesized and chemically modified from commercial increase pore volume. For first time, performance these mordenites compared with that an alkali-treated ZSM-5 for assisting simulated urban plastic waste. The...

The realization of biofuels and chemicals requires the development highly active selective catalysts, which are resistant to deactivation. A conventional ZSM-5 (SiO2/Al2O3 = 30) was modified with 0.2 M NaOH generate a mesoporous zeolite support. parent zeolite, mic-ZSM-5, hie-ZSM-5, silica support, SiO2, were impregnated 5% nickel characterized using X-ray powder diffraction (XRD), Brunauer–Emm...

In this report we discuss the synthesis and physicochemical characterizations of three zeolites with unsolved crystal structures: SSZ-57, SSZ-74, and IM-5. The diffraction data of SSZ-57 are similar to, but distinct from, the data for ZSM-5, ZSM-11, or ZSM-5/11 intergrowths. The powder diffraction data of SSZ-74 can be indexed in a unit cell with dimensions similar to those found in ZSM-5 and Z...

Abstract Biomass and waste polystyrene plastic (ratio 1:1) were co-pyrolysed followed by catalysis in a two-stage fixed bed reactor system to produce upgraded bio-oils for production of liquid fuel aromatic chemicals. The catalysts investigated ZSM-5 impregnated with different metals, Ga, Co, Cu, Fe Ni determine their influence on bio-oil upgrading. results showed that the added metals had impa...