A template-directed synthetic approach to halogen-bridged mixed-valence platinum complexes has been performed in organic media using, for instance, a synthetic peptide bearing two bis(ethylenediamine)-based Pt(IV) complexes with two axial bromide anionic ligands, [(Pt(IV)Br2(en))2](RSO3)4, and a [Pt(II)(en)2](RSO3)2 complex (R = (C12H25OCH2)2CHO(CH2)3-).

the in-situ method of synthesis has been used to isolate oxovanadium(iv) complexes with ligands derived by reaction of benzil with amino acids such as glycine, alanine, serine, cysteine and valine, where template effect of vo +2 cation appears to play an important role. the complexes are characterised by elemental analysis, magnetic moment measurements and spectral (infrared, electronic and ele...

cr2o3 nanoparticles were prepared using cr(no3)3.9h2o as starting material, triethanolamine (tea) as template and water as green solvent under microwave irradiation. the products were characterized by x-ray diffraction (xrd), transmission electron microscopy (tem), fourier transform infrared (ft-ir), photoluminescence (pl) and raman spectroscopy. the size distribution of individual particles we...

in this work, the synthesis of porous structure of cadmium oxide with multilayered sheet-like morphology in nano-meter size using adipic acid as soft template by solvothermal/thermal decomposition process is reported. chemical analyses exhibited that the formation of porous sheet-like structure is originated from bidentate coordination mode of adipate units to cd-center. it was found that the c...

coni nanowires were deposited by pulsed electrodeposition technique into porous alumina templates. the effect of off time between pulses (toff) and reductive/oxidative time (treduc/oxid) on the microstructure and magnetic properties of the coni nanowires were investigated. maximum coercivity and squareness were obtained for samples fabricated at treduc/oxid= 0.5 ms and toff =400 ms. the coerciv...

Background: Electromyographic (EMG) signals obtained from a contracted muscle contain valuable information on its activity and health status. Much of this information lies in motor unit potentials (MUPs) of its motor units (MUs), collected during the muscle contraction. Hence, accurate estimation of a MUP template for each MU is crucial. Objective: To investigate the possibility of improv...

The thermo-optical properties of coated surface are important for spacecraft thermal control coatings which depend on the optical properties and structure of the coating material. These coatings control the temperature by their capability of outer energy absorption and its emission. The optical properties of pigment can be improved if the pigment contains a high fraction of voids in its structu...