نتایج جستجو برای: metallophthalocyanine

تعداد نتایج: 49  

Journal: :Chemical communications 2012
Xuesong Ding Xiao Feng Akinori Saeki Shu Seki Atsushi Nagai Donglin Jiang

Phthalocyanine covalent organic frameworks with different central metals are synthesized, and the AA-stacking structure of the 2D polymer sheets results in periodic phthalocyanine π-columns. The central metals control the π-electronic functions, including the improvement of light absorbance, the ease of carrier transport, and the photocurrent gain.

Journal: :Dalton transactions 2011
Dilek Elmali Ahmet Altindal Ali Riza Ozkaya Bekir Salih Ozer Bekaroğlu

Novel mononuclear Zn(ii) 4, Co(ii) 5 and Cu(ii) 6 metallophthalocyanines have been synthesized from 4,4'(ethane-1,1-p-phenol-2,2-p-phenoxy)phthalonitrile 3, which can be obtained by the reaction of 4-nitrophthalonitrile 1 with 1,1,2,2-tetrakis(p-hydroxy-phenyl)-ethane 2. The target water-soluble derivatives of 7-9 were acquired from a boiling suspension of the compounds in aqueous 20% KOH solut...

Ahmad Ahaabani Ayoob Bazgir, Farzad Bahadoran Naser Safari

Phthalocyanine complexes of Cu, Co, Ni, Fe, Zn, Pd, Pt and Ru have been synthesized from reaction between phthalonitrile and proper metal salts upon exposure to microwave irradiation under solvent-free conditions and considerably reduced reaction times.

Journal: :Physical chemistry chemical physics : PCCP 2008
Bolade O Agboola Kenneth I Ozoemena

Electrochemical properties of redox-active self-assembled molecular films of novel metallo-octacarboxyphthalocyanine (MOCPc, M = Fe, Co and Mn) complexes integrated with cysteamine (Cys) monolayer on gold electrodes via amide bonds were investigated. X-Ray photoelectron spectroscopy confirmed the appearance of the various elements in their expected chemical environment upon immobilization of th...

2014
Baocheng Zhou Wenxing Chen

Amine-modified CNFs (AN-CNFs) were first obtained through the Billups reaction from carbon nanofibers (CNFs), and were used as supports of cobalt tetracarboxylphthalocyanine (CoTCPc) for the catalytic oxidation of Acid Orange 7 (AO7) in the CoTCPc-AN-CNFs/H₂O₂ system. CNFs, AN-CNFs and CoTCPc-AN-CNFs were characterized by X-ray photoelectron spectroscopy, thermogravimetric analysis, transmissio...

2016
Xiao Feng Xuesong Ding Long Chen Yang Wu Lili Liu Matthew Addicoat Stephan Irle Yuping Dong Donglin Jiang

Highly ordered discrete assemblies of chlorophylls that are found in natural light-harvesting antennae are key to photosynthesis, which converts light energy to chemical energy and is the principal producer of organic matter on Earth. Porphyrins and phthalocyanines, which are analogues of chlorophylls, exhibit a strong absorbance of visible and near-infrared light, respectively. A highly ordere...

Journal: :The journal of physical chemistry. B 2006
Karla A Miller Richard D Yang Michael J Hale Jeongwon Park Bernd Fruhberger Corneliu N Colesniuc Ivan K Schuller Andrew C Kummel William C Trogler

The electrical properties of 50 nm thick metallophthalocyanine films, prepared by organic molecular beam epitaxy (OMBE) on interdigitated electrodes, were studied with DC current-voltage measurements and impedance spectroscopy. The transition from Ohmic behavior at low voltages to space-charge-limited conductivity (SCLC) at higher voltages depends on the metal electrode (Pt, Pd, and Au), but do...

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