Stabüity Constants, Metal Ion Complexes, Oxygen Tripod Ligand The formation of metal ion complexes ML(> and ML2(>+ of the oxygen tripod ligand L~ = cyclopentadienyltris(diethylphosphito-P)cobaltate(l-) with metal ions M — Li+, Na+, K+, Mg+, Ca+, Sr+, Ba+, Mn+, Co+, Ni+, Cu+, Zn+, Cd+, Hg+, Pb+, Ag+, and La has been studied by pH titration at 25 °C in 95/5 methanol/water solutions kept at an ion...

The acidity constants of some amino acids (Am) were determined by potentiometric pH titration. The stability constants of the 1:1 complexes formed between M2+: Ca2+, Mg2+, Mn2+, Co2+, Ni2+, Cu2+ or Zn2+ and Am2-, were determined by potentiometric pH titration in aqueous solution (I = 0.1 M, NaNO3, 25°C). The order of the stability constants was reported. It is shown that the stability of the bi...

Metal coordinating comonomers influence the transition metal complex, polymer–metal ion binding, and subsequently material properties in magnetic responsive poly(ionic liquid)s.

chelating resins based on polyacrylonitrile and diethylenetriamine (pan-dta) wereprepared through the simple reaction of polyacrylonitrile with various volume percents ofdiethylenetriamine (dta), (25, 50, 75 and 100). the prepared resins were applied to removeheavy metal ions such as cu(ii), zn(ii) and cd(ii) from aqueous solutions. the sorptionbehaviors of the resins for these metal ions were ...

The antioxidant activity of flavonoids is believed to increase when they are coordinated with transition metal ions. However, the literature on this subject is contradictory and the outcome seems to largely depend on the experimental conditions. In order to understand the contribution of the metal coordination and the type of interaction between a flavonoid and the metal ion, in this study a ne...

Photo-controlled metal-ion (Zn(2+) and Cd(2+)) release in aqueous micelle solution (tris-HCl, pH = 7.4) has been described using 2-((2-mercaptophenylimino)methyl) phenol as ligand. It is found that both the ligand-Zn complex (1) and the ligand-Cd complex (2) are stable in micelle solution, and Zn(2+) (Cd(2+)) can be released from the complex with 365 nm light trigger. Accompanying the metal-ion...

in the present study, a simple and sensitive extractive spectrophotometric method is described for determination of buspirone. the method is based on the reaction of buspirone and bromocresol green. the ion-pair complex was quantitatively extracted into chloroform at ph 2.3 followed by spectrophotometric determination at 415 nm. the complex was stable up to 2 days and obeyed beer's law over the...

a simple and sensitive extractive spectrophotometric method is described for determination of tropicamide. the method is based on the reaction of tropicamide and bromocresol green. the ion-paired colored complex was extracted with chloroform at ph 3. the extracted complex showed maximum absorbance at 423 nm. the complex was stable up to 2 days and obeyed beer's law over the concentration r...