Hagelstein and Chaudhary have recently criticized our low energy nuclear reaction rates in chemical cells based on our computed electron mass renormalization for surface electrons of metal hydride electrodes. They further criticize our electron mass renormalization in exploding wire systems which is very strange because mass renormalization was never even mentioned in our exploding wire work. H...

Density functional theory (DFT) has been used to determine the geometric and electronic structure of series [cis-{(?5-C5H3)2(CMe2)2}-Ru2(CO)4(?-H)n]n+ (n = 0, 1, 2) their di-tert-butyl-bipyridine (bipy) analogs ((CO)2 bipy). The results have analyzed by using natural bond orbitals (NBO) quantum atoms in molecules (QTAIM). This provide a thorough description changes bonding that occur as Ru-Ru n...

Decoration of tetrelchalcogenide T-E clusters with chelating donor ligands was achieved to capture transition metal ions on their surfaces. We demonstrate that by covalent linking of bispyridyl ligands to an Sn-S complex, [ZnX](+) units can be trapped and incorporated into the cluster framework. Intermediates that were identified using spectroscopy and/or X-ray diffraction gave insight into the...

Using UV-vis spectrophotometic method, the formation constants for interaction of Cd2+(aq) andCo2+(aq) ions with L-Alanine were experimentally studied at pH = 4.1 ± 0.01 (50mM of potassiumhydrogen phthalate buffer), ionic strength of 0.1M potassium nitrate and at 5 differenttemperatures 15,20, 25,30 and 35°C. The optical absorption spectra of mixtures containingconsidered cations and L-Alanine ...

abstractinteraction of ni complex(salen= n, n´-ethylene bis(salicylideneimine)) with hen egg-white lysozyme (hewl) was studied by absorption spectroscopy, competitive binding study and thermal denaturation study. the protein binding affinity of ni complex was found to be (3.0×103m−1). the binding plot obtained from the absorption titration data gives a binding constant of 2.4 (± 0.3)×103 m-1. i...