[reaction: see text] A large and normal nitrogen-15 kinetic isotope effect of 1.035 +/- 0.003 provides direct support for the proposed mechanism for the rhodium-catalyzed carbene formation from diazo compounds, which involves the fast formation of a metal-diazo complex followed by rate-limiting extrusion of N2. The large magnitude of the KIE indicates extensive C-N bond fission in the transitio...

hot-melt extrusion is one of the most widely applied processing technologies in the plastic, rubber and food industry. today this technology has found its place in the array of pharmaceutical manufacturing operations. melt extrusion process are currently applied in the pharmaceutical field for the manufacture of a variety of dosage forms and formulations such as granules, pellets, tablets, supp...

Abstract This study proposes FEM simulation on forward extrusion of bi-metal rod comprised Aluminum (Core) and Copper (Sleeve). A Deform-2D commercial software with constant shear friction is used to explore the forming characteristics, such as effective stress, strain, velocity field, force, die ratio inner diameter outer at exit after deformation (the aspect ratio). Besides forces obtained by...

A variety of transition-metal complexes with terminal silylene ligands have become available in recent years, because of the discovery of several preparative methods. In particular, three general synthetic routes to these complexes have emerged, on the basis of anionic group abstraction, coordination of a free silylene, and alpha-hydrogen migration. The direct transformation of organosilanes to...

Slab method of analysis has been used for solving metal forming problems for a long time. However it has been restricted to plane strain and axisymmetric problems due to limitations in its formulations. In this paper a new formulation has been proposed so that it could be applied to three dimensional problems in metal forming. A parametric slab has been considered in this analysis and the force...

The effects of hydrostatic extrusion on particle cracking and on the subsequent tensile properties of some prototypical particlereinforced metal–matrix composites are investigated. In most cases, tensile failure occurs through a plastic instability in accordance with the Considere criterion for necking. The corresponding failure strain is therefore dictated by the global flow and hardening char...